Wiley Online Library : ChemSusChem
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TpPa‐1 COFs‐Enhanced Zwitterion Hydrogel for Efficient Harvesting of Atmospheric Water

A zwitterionic hydrogel of PCL composite is synthesized by a situ free radical polymerization method and a impregnation method. The PCL composite hydrogel has a gradient pore structure, which may accelerate the transport of water molecules, increase the loading capacity of LiCl and enhance the photothermal property. The optimal composite hydrogel...

Sat Apr 20, 2024 11:57
Mo3S13 Chalcogel: A High‐Capacity Electrode for Conversion‐Based Li‐Ion Batteries

This study showcases the synthesis and analysis of the local structure of amorphous Mo3S13 within chalcogel matrix and underscores its potential as high-capacity electrode for Li-ion battery applications. Abstract Despite large theoretical energy densities, metal-sulfide electrodes for energy storage systems face several limitations that impact...

Sat Apr 20, 2024 11:57
Facile Synthesis of Dithienobenzothiadiazoles and D18−Cl Polymer via Na2S‐Mediated Rapid Thiophene‐Annulations for Organic Solar Cells

A novel two-step synthetic route for dithienobenzothiadiazoles (DTBTs) from commercially available 4,7-dihalo-5,6-difluorobenzo[c][1,2,5]thiadiazole was developed. A key strategy for this transformation lies on Na2S promoted thiophene-annulations of 4,7-dialkynyl-5,6-difluorobenzo[c][1,2,5]thiadiazoles. Our protocol for DTBT synthesis features a mild...

Sat Apr 20, 2024 11:57
Manganese Oxide / Silica catalysed Decarboxylative Ketonization of Aliphatic Carboxylic Acids in a Continuous Flow Reactor

The sustainable synthesis of long carbon chain molecules from carbon dioxide, water and electricity relies on the development of waste-free, highly selective C–C bond forming reactions. An example for such a power-to-chemicals process is the industrial-scale fermentation for the production of hexanoic acid. Herein, we describe how this product is transformed...

Sat Apr 20, 2024 11:57
Unveiling a Novel Decomposition Pathway in Propylene Carbonate‐Based Supercapacitors: Insights from a Jelly Roll Configuration Study

This research elucidates novel insights into the electrochemical properties and degradation phenomena of propylene carbonate (PC)-based supercapacitors at a large-scale 18650 cylindrical jelly-roll cell level. Central to our findings is the identification of 2-ethyl-4-methyl-1,3-dioxolane (EMD) as a hitherto undocumented decomposition by-product, highlighting...

Fri Apr 19, 2024 11:06
Manganese Oxide / Silica catalysed Decarboxylative Ketonization of Aliphatic Carboxylic Acids in a Continuous Flow Reactor

The sustainable synthesis of long carbon chain molecules from carbon dioxide, water and electricity relies on the development of waste-free, highly selective C–C bond forming reactions. An example for such a power-to-chemicals process is the industrial-scale fermentation for the production of hexanoic acid. Herein, we describe how this product is transformed...

Fri Apr 19, 2024 11:06

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