Stereochemical expression of <i>ns</i>² electron pairs in metal halide perovskites

Nature Reviews Chemistry, Published online: 23 November 2021; doi:10.1038/s41570-021-00335-9This Review establishes a unifying structure–property relationship among chemical composition, centrosymmetry breaking, lattice anharmonicity, ferroelectricity, dielectric screening and the Rashba effect in metal halide perovskites from the perspective of stereochemical...

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Stereochemical expression of <i>ns</i>² electron pairs in metal halide perovskites

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Advances and opportunities in the exciting world of azobenzenes

Nature Reviews Chemistry, Published online: 18 November 2021; doi:10.1038/s41570-021-00334-wOver the past decade, advances in azobenzenes have revolutionized their application potential, going beyond traditional uses as dyes and ultraviolet photoswitches. This Review describes breakthroughs in the development of red-light-photoswitchable azobenzenes...

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Advances and opportunities in the exciting world of azobenzenes

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An alternate route to selectivity

Nature Reviews Chemistry, Published online: 17 November 2021; doi:10.1038/s41570-021-00344-8Rapidly alternating the polarity of electrodes offers a new opportunity for synthetic chemists to obtain selective reaction outcomes in organic electrosynthesis.

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An alternate route to selectivity

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A silicon solution

Nature Reviews Chemistry, Published online: 12 November 2021; doi:10.1038/s41570-021-00342-wA silicon-linker that tethers a diyne and a diynophile provides new mechanistic insight and control of hexadehydro-Diels–Alder (HDDA) reactions.

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A silicon solution

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Using iron to catch a ride

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Using iron to catch a ride

Nature Reviews Chemistry, Published online: 10 November 2021; doi:10.1038/s41570-021-00341-xSynthetic siderophore-antibiotic conjugates can afford promising antibiotic profiles against ESKAPE pathogens and unique resistant mechanisms.

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