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Correlating ligand-to-metal charge transfer with voltage hysteresis in a Li-rich rock-salt compound exhibiting anionic redox

Nature Chemistry, Published online: 16 September 2021; doi:10.1038/s41557-021-00775-2The use of anionic redox chemistry in high-capacity Li-rich cathodes is being hampered by voltage hysteresis, the origin of which remains obscure. Now it has been shown that sluggish ligand-to-metal charge transfer kinetically traps an intermediate Fe4+ species and...

Wittig reagents for chemoselective sulfenic acid ligation enables global site stoichiometry analysis and redox-controlled mitochondrial targeting

Nature Chemistry, Published online: 16 September 2021; doi:10.1038/s41557-021-00767-2Triphenylphosphonium ylides (Wittig reagents) that selectively react with sulfenic acids—a pivotal post-translational cysteine modification in redox biology—are developed. This bioconjugation method enables a site-specific proteome-wide stoichiometry analysis of S-sulfenylation,...

Wittig reagents for chemoselective sulfenic acid ligation enables global site stoichiometry analysis and redox-controlled mitochondrial targeting

Correlating ligand-to-metal charge transfer with voltage hysteresis in a Li-rich rock-salt compound exhibiting anionic redox

Author Correction: Cyclic polyacetylene

Nature Chemistry, Published online: 14 September 2021; doi:10.1038/s41557-021-00809-9Author Correction: Cyclic polyacetylene

Author Correction: Cyclic polyacetylene

A proteome-wide atlas of lysine-reactive chemistry

Nature Chemistry, Published online: 09 September 2021; doi:10.1038/s41557-021-00765-4A deep chemical proteomic investigation of diverse aminophilic electrophiles has identified ligandable lysines across a wide range of human proteins. The proteins cover different functional and structural classes, and the aminophilic electrophiles include compounds...

Author Correction: Heat flows in rock cracks naturally optimize salt compositions for ribozymes

Nature Chemistry, Published online: 09 September 2021; doi:10.1038/s41557-021-00808-wAuthor Correction: Heat flows in rock cracks naturally optimize salt compositions for ribozymes

Author Correction: Heat flows in rock cracks naturally optimize salt compositions for ribozymes

A proteome-wide atlas of lysine-reactive chemistry

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