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RSC - Dalton Trans. latest articles

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Synthesis, Structure and Aromaticity of Metallapyridinium Complexes

Dalton Trans., 2022, Accepted ManuscriptDOI: 10.1039/D1DT04096K, PaperYilun Wang, Yue Sun, Wei Bai, Yan Zhou, Xiao Bao, Li YangThe first rhena-analogues of pyridinium (cyclopropametalla-2-isoquinolinium complexes) are obtained from o-ethynyl benzonitriles. Structural analysis and DFT calculations confirm their aromatic nature. Compared to rhenapyrylium,...

Design of an antenna effective Eu(III)-based metal-organic framework for highly selective sensing of Fe3+

Dalton Trans., 2022, Accepted ManuscriptDOI: 10.1039/D1DT03995D, PaperJiaqi Wu, Xin-Yue Ma, Chenglong Liang, Jian-Mei Lu, qian shi, Li-Xiong ShaoHighly selective sensing of Fe3+ is very important due to their great effect on biological systems. A novel ligand 1,1':4',1'':4'',1''':4''',1''''-quinquephenyl]-2,2'',2'''',5''-tetracarboxylic acid (H4qptca)...

Nucleophilic addition reactions to nitrilium derivatives [B12H11NCCH3]- and [B12H11NCCH2CH3]-. Synthesis and structure of closo-dodecaborate-based iminols, amides and amidines

Dalton Trans., 2022, Accepted ManuscriptDOI: 10.1039/D1DT04174F, CommunicationLaskova Julia, Ivan V. Ananyev, Irina Kosenko, Alexander Serdyukov, Marina Yu. Stogniy, Igor B. Sivaev, Mikhail A. Grin, Andrey Semioshkin, Vladimir I BregadzeThe synthesis of the acetonitrilium and propioitrilium derivatives of closo-dodecaborate [B12H12]2- were discussed....

Rhenium-catalysed reactions in chemical synthesis: selected case studies

Dalton Trans., 2022, Accepted ManuscriptDOI: 10.1039/D1DT04205J, PerspectiveAngus Olding, Meiqiong Tang, Curtis Craig Ho, Rebecca Olivia Fuller, Alex C. BissemberThis Perspective presents and discusses a selection of examples that reinforce the enabling and distinctive reactivity provided by homogeneous rhenium catalysis in chemical synthesis. Specifically,...

Recent advances in the chemistry of the phosphaethynolate and arsaethynolate anions

Dalton Trans., 2022, Accepted ManuscriptDOI: 10.1039/D1DT03994F, PerspectiveSuma Basappa, Ramesh Bhawar, Doddahalli H. Nagaraju, Shubhankar Kumar BoseOver the past decade, the reactivity of 2-phosphaethynolates (OCP¯), a heavier analogue of the cyanate anion, is the subject of momentous interest in modern organometallic chemistry. Its use as a...The...

B-O-B Bridged BOPPY Derivatives: Synthesis, Structures, and Acid-Catalyzed Cis-Trans Isomeric Interconversion

Dalton Trans., 2022, Accepted ManuscriptDOI: 10.1039/D1DT04203C, PaperSisi Wang, Zhaoli Wang, Wenting Song, Hu Gao, Fan Wu, Yue Zhao, Kin Shing Chan, Zhen ShenA new class of BOPPY derivatives has been facilely synthesized by a two-step reaction of coupling 3,5-dimethylpyrrole-2-carbaldehyde with 2,3-dihydrazinoquinoxaline (QDH) followed by coordinating...

Idiosyncratic recognition of Zn2+ and CN- using Pyrazolyl-Hydroxy-Coumarin scaffold and live cell imaging: Depiction of Luminescent Zn(II)-Metallocryptand

Dalton Trans., 2022, Accepted ManuscriptDOI: 10.1039/D1DT03654H, PaperSukanya Paul, Suvendu Maity, Satyajit Halder, Basudeb Dutta, Srikanta Jana, Kuladip Jana, Chittaranjan SinhaMulti-responsive sensitive and selective sensor design is one of the stimulating researches in sensor field. We have designed a pyrazolyl-hydroxy-coumarin scaffold, 7-hydroxy-4-methyl-8-(((5-phenyl-1H-pyrazol-3-yl)imino)methyl)-2H-chromen-2-one...

Near-infrared emitting copper(I) complexes with a pyrazolylpyrimidine ligand: exploring relaxation pathways

Dalton Trans., 2022, Accepted ManuscriptDOI: 10.1039/D1DT04325K, PaperNikita Shekhovtsov, T. E. Kokina, Katerina A. Vinogradova, Andrei Yu. Panarin, Marianna I Rakhmanova, Dmitry Y. Naumov, Natalie V. Pervukhina, Elena B Nikolaenkova, Viktor P Krivopalov, Rafał Czerwieniec, Mark B BushuevMononuclear copper(I) complexes [CuL2]I (1), [CuL2]2[Cu2I4]·2MeCN...

Synergistic effect of MoO2/CeO2 S-scheme heterojunction on carbon rods for enhanced photocatalytic hydrogen evolution

Dalton Trans., 2022, Accepted ManuscriptDOI: 10.1039/D1DT03605J, PaperXuanpu Wang, Teng Li, PENGFEI ZHU, Zhiliang JinThe separation efficiency of photogenerated carriers is a key factor affecting photocatalytic hydrogen evolution activity. However, loading precious metals is a cost problem, so this work introduces cheap carbon rods...The content of...

Biological luminescent metal-organic framework with high fluorescence quantum yield for the selective detection of amino acids and monosaccharides

Dalton Trans., 2022, Accepted ManuscriptDOI: 10.1039/D1DT03249F, PaperYing-Ying Zhou, Yuan Xu, Maoxing Yu, Yi Xiong, Xun-Gao Liu, Zujin ZhaoThe biological luminescent metal-organic framework (bio-LMOF), (Me2NH2)2[Zn6O(Ade)4(TCPPE)2] (1) {H4TCPPE = tetrakis[4-(4-carboxyphenyl)phenyl]ethene, Ade = adenine} was successfully designed and synthesized under...

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