Plasmonic-Assisted Photocatalytic CO2 Reduction on Au Decorated ZrO2 Catalysts

Dalton Trans., 2021, Accepted ManuscriptDOI: 10.1039/D1DT00385B, CommunicationMeng Gu, Dong Liu, Tao Ding, Xiaokang Liu, Tao Chen, Xin yi Shen, Tao YaoZrO2 is one of the most stable metal oxides which is applicable to various chemical reactions in harsh environments. However, the photocatalytic performance of ZrO2 is relatively poor due to...The content...

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Formation of an Ag-->Al Dative Bond Is Avoided in Reactions of an Alane/tris(phosphine) Ligand with Monovalent Silver

Dalton Trans., 2021, Accepted ManuscriptDOI: 10.1039/D1DT01068A, CommunicationQingheng Lai, Nattamai Bhuvanesh, Jia Zhou, Oleg V OzerovAn alane/tris(phospine) ligand reacts with AgOTf by coordination of three phosphines to the Ag center and transfer of triflate to the tris(pyrrolyl) Al site. Reaction with Ag[HCB11Cl11] results in the...The content of...

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Keep it tight: a crucial role of bridging phosphine ligands in the design and optical properties of multinuclear coinage metal complexes

Dalton Trans., 2021, Accepted ManuscriptDOI: 10.1039/D1DT00749A, PerspectiveAleksandra V. Paderina, Igor O Koshevoy, Elena V. GrachovaThe copper subgroup metal ions in the oxidation state +1 are classical candidates for the aggregation via non-covalent metal–metal interactions, which are supported by a number of the bridging ligands....The content of...

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Origin of the Ir-Si Bond Shortening in Ir-NSiN complexes

Dalton Trans., 2021, Accepted ManuscriptDOI: 10.1039/D1DT00473E, PaperPilar García-Orduña, Israel Fernandez, Luis A Oro, Francisco J Fernandez-AlvarezThe Ir-Si bond distances reported for Ir-(fac-k3-NSiNOPy) and Ir-(fac-k3-NSiN4MeOPy) species (NSiNOPy = bis(pyridine-2-yloxy)methylsilyl and NSiN4MeOPy = bis(4-methyl-pyridine-2-yloxy)methylsily) are in...

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Low temperature synthesis of barium oxynitridosilicates using BaCN2 and SiO2

Dalton Trans., 2021, Accepted ManuscriptDOI: 10.1039/D1DT00824B, PaperYuji Masubuchi, Naoki Sada, Yoshiteru Kawahara, Kenji Arai, Teruki Motohashi, Mikio HiguchiBarium oxynitridosilicates, Ba3Si6O12N2 and Ba3Si6O9N4, were obtained from a mixture of BaCN2 and SiO2 at 800 °C, which is several hundred degrees lower than that required in solid state reactions...The...

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Metal-organic Framework-derived Zn1-xCdxS/CdS Heterojunction for Efficient Visible Light-driven Photocatalytic Hydrogen Production

Dalton Trans., 2021, Accepted ManuscriptDOI: 10.1039/D1DT00667C, CommunicationTianyu Bai, Xiaofan Shi, Ming Liu, Hui Huang, Mei-Hui Yu, Jijie Zhang, Xian-He BuThe ZCS-C (ZnCdS/CdS) QDs are synthesized via low-temperature vulcanization with zeolitic imidazolate framework-8 (ZIF-8) nanoparticles as a precursor, cation exchange, and heterojunction construction....

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Uniform decoration of UiO-66-NH2 nanooctahedra onto TiO2 electrospun nanofibers for enhancing photocatalytic H2 production based on multi-step interfacial charge transfer

Dalton Trans., 2021, Accepted ManuscriptDOI: 10.1039/D1DT00743B, PaperJie Wang, Zhen-Gang Sun, Xiaoyi Jiang, Qing Yuan, Da-Peng Dong, Peng Zhang, Zhenyi ZhangMetal-organic frameworks (MOFs) materials have been extensively incorporated with inorganic semiconductor photocatalysts to improve the photocatalytic activity through an efficient charge transfer...

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Contact resistance stability and cation mixing in Vulcan-based LiNi1/3Co1/3Mn1/3O2 slurry for semi-solid flow batteries

Dalton Trans., 2021, Accepted ManuscriptDOI: 10.1039/D1DT00495F, PaperJordi Jacas Biendicho, Hemesh Avireddy, Victor Izquierdo-Roca, Cristina Flox, Joan R. MoranteThe Semi-Solid Flow Battery (SSFB) is an interesting energy storage system (ESS) for stationary applications but, in spite of the significant work presented on this technology so far, understanding...

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Conversion of Pd(I) off-cycle species into highly-efficient cross-coupling catalysts

Dalton Trans., 2021, Accepted ManuscriptDOI: 10.1039/D1DT00929J, CommunicationSteven P Nolan, Catherine Cazin, Luigi Cavallo, Thomas Scattolin, Vladislav Voloshkin, Yaxu Liu, Busra DereliWe report on the facile conversion of [Pd2(μ-Cl)(μ-η3-R-allyl)(NHC)2] complexes, which are commonly considered undesirable off-cycle species in cross-coupling reactions,...

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Interaction of Dicoordinate Phosphorus with Boranes: Chemistry of 3a,6a-Diaza-1,4-diphosphapentalene as Masked Phosphinidene

Dalton Trans., 2021, Accepted ManuscriptDOI: 10.1039/D1DT00747E, PaperYulia Panova, Alexandra Khristolyubova, Natalya Zolotareva, Vyacheslav Sushev, Vadim Galperin, Roman V. Rumyantcev, Georgii K Fukin, Alexander KornevTreatment of 3a,6a-diaza-1,4-diphosphapentalene (DDP) with an excess of PhBCl2 yields the corresponding bis(borane) adduct DDP(PhBCl2)2...

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