Synthesis and catalytic activity of palladium complexes bearing N-heterocyclic carbenes (NHCs) and 1,4,7-triaza-9-phosphatricyclo[5.3.2.1]tridecane (CAP) ligands

Dalton Trans., 2021, Accepted ManuscriptDOI: 10.1039/D1DT01716K, PaperSteven P Nolan, Thomas Scattolin, Vladislav Voloshkin, Ekaterina A. Martynova, Sofie Vanden Broeck, Marek Belis, Catherine CazinThe synthesis and characterization of novel palladium complexes bearing N-heterocyclic carbenes (NHCs) and 1,4,7-triaza-9-phosphatricyclo [5.3.2.1] tridecane...

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Dual role of silver in a fluorogenic N-squaraine probe based on Ag(I)-π interactions

Dalton Trans., 2021, Accepted ManuscriptDOI: 10.1039/D1DT01408K, CommunicationManel Vega, Salvador Blasco, Enrique García-España, Bartolome Soberats, Antonio Frontera, Carmen Rotger, Antonio CostaIn the presence of Ag(I), the monoanion of a cyano-N-squaraine (I) generates an intense fluorescent turn-on response. Experimental evidence and DFT calculations...

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Cyclometalated Ir(III) complexes as potential electron acceptors for organic solar cells

Dalton Trans., 2021, Accepted ManuscriptDOI: 10.1039/D1DT01136G, PaperYoutian Tao, Tianjian Yang, Yinming He, Yang Cheng, Xuyu Gao, Yijing Wu, Wenbo YuanCyclometalated Iridium(III) complexes have been investigated as promising electron donor (D) materials in organic solar cells (OSCs) due to the unique octahedral configuration for optimized morphology...

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Noninnocence of deprotonated 1,2-bis((1H-pyrrol-2-yl)methylene) hydrazine bridge in diruthenium frameworks-a function of co-ligands

Dalton Trans., 2021, Accepted ManuscriptDOI: 10.1039/D1DT01488A, PaperGoutam Kumar Lahiri, Sudip Kumar Bera, Maya KumariThe article dealt with the sensitive electronic forms in accessible redox states of structurally and spectroscopically authenticated deprotonated 1,2-bis((1H-pyrrol-2-yl)methylene) hydrazine (H2LR, R=H) or 1,2-bis((3,5-dimethyl-1H-pyrrol-2-yl)methylene)hydrazine...

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Boosting charge transfer of FeOOH/Ni(OH)2 for excellent oxygen evolution reaction via Cr modification

Dalton Trans., 2021, Accepted ManuscriptDOI: 10.1039/D1DT01469B, PaperYan He, tao yu, Hui Wen, Rui GuoFor electrocatalytic oxygen evolution reaction (OER) in alkaline media, it is urgently needed to optimize the adsorption strength of OH*. Here, a flower-like hybrid of Cr-doped FeOOH/Ni(OH)2 was used as...The content of this RSS Feed (c) The Royal Society...

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Designing the water-quenching resistant high luminescent europium complexes by regulating the orthogonal arrangement of bis-β-diketone ligands

Dalton Trans., 2021, Accepted ManuscriptDOI: 10.1039/D1DT00155H, PaperMei Li, Yanyan Zhou, Yuan Yao, Ting Gao, Pengfei Yan, Hongfeng LiLuminescent β-diketone-based lanthanide complexes have been well explored as chemical sensor materials for biomedicine applications. Herein, three mononuclear Eu3+ complexes based on bis-β-diketone ligands (L1, L2 and...

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Double α,α CH Bond Insertion into sp3 CH2 Moiety: Synthesis of a Fe Carbene bis-Hydride Dinitrogen Complex.

Dalton Trans., 2021, Accepted ManuscriptDOI: 10.1039/D1DT00610J, PaperJulien Petit, Anthony Cavaillé, Nathalie Saffon, Marie Fustier-Boutignon, Nicolas MézaillesReduction of high spin paramagnetic complex [(κ2-P, P’-PCH2PCy)FeCl2] 2 by two electrons under N2 resulted in the formation of two isomeric low spin diamagnetic complexes 3trans and 3cis [Fe(κ3-P,C,P’-PCPCy)(H)2(N2)]....

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Combined therapy of ruthenium dendrimers and anti-cancer drugs against human leukemic cells

Dalton Trans., 2021, Accepted ManuscriptDOI: 10.1039/D1DT01388B, PaperSylwia Michlewska, Marta Maroto, Marcin Hołota, Małgorzata Kubczak, Natalia Sanz del Olmo, Paula Ortega, Dzmitry Shcharbin, F. Javier De la Mata, Maria Bryszewska, Maksim IonovCarbosilane ruthenium(II) dendrimers have been complexed with conventional anti-cancer drugs. Due to its...

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Well-Dispersed Te-Doped Mesoporous Carbons as Pt-Free Counter Electrode for High-Performance Dye-Sensitized Solar Cells

Dalton Trans., 2021, Accepted ManuscriptDOI: 10.1039/D0DT04372A, PaperHwan Kyu Kim, Jung-Min Ji, Chang Ki KimTellurium-doped carbon nanomaterial (Te-MC(P)) was newly developed by the soft-templated carbonization of PAN-b-PBA copolymer with poly(3-hexyltellurophene). The Te-MC(P) was characterized with various characterizations, including the nitrogen...

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Phthalocyanine-grafted MA-VA framework polymer as high performance anode material for lithium/sodium-ion batteries

Dalton Trans., 2021, Accepted ManuscriptDOI: 10.1039/D1DT01400E, PaperJianjun Zhao, Yong Xu, Jun Chen, Lihong Tao, Caixia Ou, Weixia Lv, Shengwen ZhongA porous MA-VA-PcNi polymer was prepared by grafting nickel phthalocyanine (PcNi) onto the main chain of maleic anhydride-vinyl acetate (MA-VA) polymer, and the MA-VA-PcNi electrode is prepared by electrospinning...

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