Highly efficient catalytic transfer hydrogenation of furfural over defect-rich amphoteric ZrOtext-decoration:underline"2 with abundant surface acid-base sites

Dalton Trans., 2021, Accepted ManuscriptDOI: 10.1039/D0DT00055H, PaperZekun Zhu, Lingling Yang, Changxuan Ke, Guoli Fan, Lan Yang, Feng LiCurrently, the catalytic transformation and utilization of biomass-derived compounds is of great importance to the alleviation of environmental problems and sustainable development. Among them, furfural alcohol derived...

2h

Mono-N-oxidation of Heterocycle-Fused Pyrimidines

Dalton Trans., 2021, Accepted ManuscriptDOI: 10.1039/D0DT03260C, PaperJean'ne M. Shreeve, Yongxing Tang, Kejia Li, Ajay Kumar Chinnam, Richard J. StaplesThree nitrogen-rich heterocyclic compounds containing the diamino-pyrimidine mono-N-oxide moiety were synthesized via mild oxidation reactions. Oxidation of the furazano-pyrimidine compound (1) with...

9h

Molecular 1,1’-bifunctional mixed-valence P-P compounds, enabled through metal complexation

Dalton Trans., 2021, Accepted ManuscriptDOI: 10.1039/D0DT04070C, PaperAlexander Schmer, Antonio Bauza, Gregor Schnakenburg, Antonio Frontera, R. StreubelMixed-valence compounds feature same atoms but in different formal oxidation states. This research field is largely dominated by metal-based solid-state chemistry and has been intensively studied in...

9h

Photodynamic activity of Sn(IV) tetrathien-2-ylchlorin against MCF-7 breast cancer cells

Dalton Trans., 2021, Accepted ManuscriptDOI: 10.1039/D0DT03958F, PaperBalaji Babu, John Mack, Tebello NyokongA new readily-synthesized Sn(IV) tetraarylchlorin with thien-2-yl substituents (SnC) has been synthesized and fully characterized by various spectroscopic techniques and its photophysical and photochemical properties, such as the singlet oxygen...The...

14h

Solid-state redox couple mediated water splitting

Dalton Trans., 2021, Accepted ManuscriptDOI: 10.1039/D0DT03893H, FrontierDuanduan Liu, Wei Wei, Mahemu Maidina, Hao Qin, Kai Zhu, Shicheng Yan, Zhigang ZouSolid-state redox couple is a vital charge transfer medium for electrochemical water splitting. In this Frontier article, we summarized the versatile efforts of redox couple in promoting OER kinetics,...

16h

Synthesis, Characterization, and Alkoxide Transfer Reactivity of Dimeric Tl2(OR)2 Complexes

Dalton Trans., 2021, Accepted ManuscriptDOI: 10.1039/D0DT03917A, PaperStanislav Groysman, Amanda Grass, Duleeka Wannipurage, Lakshani Wathsala Kulathungage, Maryam Yousif, Cassandra L WardReaction of LiOCtBu2Ph with TlPF6 forms the dimeric Tl2(OCtBu2Ph)2 complex, a rare example of a homoleptic thallium alkoxide complex demonstrating formally two-coordinate...

16h

Synthesis and reactivity of iridium complexes of a macrocyclic PNP pincer ligand

Dalton Trans., 2021, Accepted ManuscriptDOI: 10.1039/D0DT04303F, Paper Open Access   This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Thomas M Hood, Adrian B ChaplinHaving recently reported on the synthesis and rhodium complexes of the novel macrocyclic pincer ligand PNP-14, which is derived from lutidine...

18h

Unexpected binuclear O−O cleavage and radical C−H activation mechanism for Cu-catalyzed desaturation of lactone

Dalton Trans., 2021, Accepted ManuscriptDOI: 10.1039/D0DT04311G, PaperZhiyun Hu, Xinzheng YangDensity functional theory study of Cu-catalyzed desaturation of δ-valerolactone into α,β-unsaturated counterparts reveals an unexpected binuclear di-tert-butyl peroxide (DTBP) homolysis with spin-crossover and radical α-C−H bond activation mechanism. The rate-determining...The...

19h

Enhanced lithium storage performance of porous Si/C composite anodes through using recrystallized NaCl template

Dalton Trans., 2021, Accepted ManuscriptDOI: 10.1039/D0DT03911J, PaperYe Hong, Haiyong Dong, Jianhong Li, Qianqian Hu, Zilong Tang, Jian Ouyang, Xiaojun Wang, Dan XiangSilicon (Si) has recently aroused great interest as a promising anode material for lithium-ion batteries with high energy density due to its high theoretical capacity. However, it remains...

19h

Temperature dependence of desolvation effects in hydrogen-bonded spin crossover complexes

Dalton Trans., 2021, Accepted ManuscriptDOI: 10.1039/D0DT03986A, PaperVerónica Jornet-Mollá, Carlos Giménez-Saiz, Bruno J. C. Vieira, João Waerenborgh, Francisco M. RomeroThe synthesis, crystal structure and (photo)magnetic properties of the anhydrous spin crossover salt of formula [Fe(bpp)2](C6H8O4) (1)(bpp = 2,6-bis(pyrazol-3-yl)pyridine; C6H8O4 =...

19h