Low temperature thermal ALD process for nickel utilizing dichlorobis(triethylphosphine)nickel(II) and 1,4-bis(trimethylgermyl)-1,4-dihydropyrazine

Dalton Trans., 2022, Accepted ManuscriptDOI: 10.1039/D2DT01347A, Paper Open Access   This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.Anton Vihervaara, Timo Hatanpää, Kenichiro Mizohata, Mykhailo Chundak, Georgi Popov, Mikko RitalaIn this work, we developed a new ALD process for nickel metal from dichlorobis(triethylphosphine)nickel(II)...

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High yield of a variety of silicon-boron radicals and their reactivity

Dalton Trans., 2022, Accepted ManuscriptDOI: 10.1039/D2DT01318E, Paper Open Access   This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Herbert W Roesky, Mohd Nazish, Yi Ding, Christina M. Legendre, Arun Kumar, Nico Graw, Brigitte Schwederski, Regine Herbst-Irmer, Parvathy P, Pattiyil Parameswaran, Dietmar...

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Phosphorus-doped potassium peroxyniobate electrocatalyst with enriched oxygen vacancy boosts electrocatalytic nitrogen reduction to ammonia

Dalton Trans., 2022, Accepted ManuscriptDOI: 10.1039/D2DT01501C, PaperShuhui Fan, Fei Zhao, Xuansheng Wang, Qi Wang, Qiang Zhao, Jinping Li, Guang LiuElectrochemical ammonia synthesis is an environmentally friendly method for ammonia production, but still impeded by the bottleneck of N2 activation and challenging hydrogen evolution reaction (HER). Rational...

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Phase-sensitive radioluminescent and photoluminescent features in Tm3+-doped yttrium tantalates for cyan and white light generation

Dalton Trans., 2022, Accepted ManuscriptDOI: 10.1039/D2DT01455F, PaperHayra do Prado Labaki, Fábio José Caixeta, Natasha Policei Marques, Eder Jose Guidelli, Rogéria Rocha GonçalvesRadioluminescence and visible photoluminescent tunability features from a single Tm3+-doped yttrium tantalate phosphor prepared by a soft sol–gel method designed to afford...

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Encapsulating electron-deficient dyes into Metal-Organic Capsules To Achieve High Reduction Potentials

Dalton Trans., 2022, Accepted ManuscriptDOI: 10.1039/D2DT01166B, CommunicationJiayou Yuan, Zhong Wei, Keshen Shen, Yang Yang, Mingxu Liu, Xu Jing, Chunying DuanThe design of artificial supramolecular systems that mimic the structure and functionality of natural enzymes to achieve efficient chemical conversions is a promising subject. In this work, we...

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Synthesis, solid-state, solution, and theoretical characterization of an “in-cage” scandium-NOTA complex

Dalton Trans., 2022, Advance ArticleDOI: 10.1039/D1DT03887G, Paper Open Access   This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.Kelly E. Aldrich, Ivan A. Popov, Harrison D. Root, Enrique R. Batista, Samuel M. Greer, Stosh A. Kozimor, Laura M. Lilley, Maksim Y. Livshits, Veronika Mocko, Michael T. Janicke, Brian L....

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Visible and near-infrared luminescent properties of Nd3+/Yb3+ co-doped Gd2O3 phosphor for highly sensitive optical thermometry

Dalton Trans., 2022, Accepted ManuscriptDOI: 10.1039/D2DT01271E, PaperYuhong Zhang, Pengcheng Wang, Haiyan Wang, Xingke Zheng, Yibin Guo, Nan Zhang, Hang LiuPhosphors with rare earth (RE) ions are widely applied to optical temperature measurement. Moreover, the near-infrared (NIR) emission of phosphor has potential applications at biological field....

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Synthesis and structural characterization of copper-cuprizone complexes

Dalton Trans., 2022, Accepted ManuscriptDOI: 10.1039/D2DT01475K, PaperM. Jake Pushie, Kelly Summers, Kurt H Nienaber, Ingrid Pickering, Graham GeorgeCopper(II) coordination by bis(cyclohexanone)oxalyldihydrazone (also known as cuprizone), resulting in the formation of an intensely coloured blue complex, was first reported over 70 years ago. The cuprizone...

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Informing our Understanding of the Copper-Cuprizone Reaction with Computational Chemistry

Dalton Trans., 2022, Accepted ManuscriptDOI: 10.1039/D2DT01476A, PaperM. Jake Pushie, Graham GeorgeThe reaction of copper with bis(cyclohexanone)oxaldihydrazone (cuprizone) is a challenging coordination chemistry problem that has confounded attempts at elucidation for the past 70 years. The product of the reaction, a...The content of this RSS Feed (c)...

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Modulating the reactivity of phosphanylidenephosphoranes towards water with Lewis acids

Dalton Trans., 2022, Accepted ManuscriptDOI: 10.1039/D2DT01575G, PaperFabian Dankert, Malte Fischer, Christian Hering-JunghansPhosphanylidenephosphoranes of the type R−P(PR’3), also known as phospha-Wittig reagents, can be utilized in a variety of bond activation reactions exploiting their phosphinidenoid reactivity. In here, we thoroughly show that...The...

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