Higher stability within metalloid tin clusters via Cation-Anion interaction.

Dalton Trans., 2021, Accepted ManuscriptDOI: 10.1039/D1DT02591K, PaperAndreas Schnepf, Claudio Schrenk, Roman KimmichThe reaction of a metastable SnCl solution with KR (R = Si(SiMe3)2(SitBuMe2) = HyptBuMe2 or Si(SiMe3)2(SiEt3) = HypEt3) gives the metalloid tin clusters [Sn10R4]2− in partly good yields. The tin...The content of this RSS Feed (c) The...

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Bifunctional application of La3BWO9:Bi3+, Sm3+ phosphors with strong orange-red emission and sensitive temperature sensing properties

Dalton Trans., 2021, Accepted ManuscriptDOI: 10.1039/D1DT02292J, PaperWeiguang Ran, Guangshi Sun, Xiaoli Ma, Liyun Zhang, Jae Su Yu, Hyeon Mi Noh, Byung Chun Choi, Jung Hyun Jeong, Tingjiang YanThrough solid-phase reaction technique, Sm3+ and Bi3+ co-doped La3BWO9 phosphors with high emission intensity and sensitive temperature sensing properties have...

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Thermally stable vanadium complexes supported by the iminophenyl oxazolinylphenylamines ligands: Synthesis, characterization and application for ethylene (co-)polymerization

Dalton Trans., 2021, Accepted ManuscriptDOI: 10.1039/D1DT03004C, PaperRuiyao Wu, Zhen Niu, Lingyun Huang, Yinxin Yang, Zhu Xia, Weifeng Fan, Quanquan Dai, Long Cui, Jianyun He, Chenxi BaiIn this work, a series of oxovanadium complexes bearing ligands (S, E)-(+)-2, 6-dialkyl-N-(2-( (2-(4-isopropyl-4, 5-dihydrooxazol- 2-yl) phenyl)amino)benzylidene)aniline...

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T-Nb2O5 nanoparticles confined in carbon nanotubes with fast ion diffusion rate for lithium storage

Dalton Trans., 2021, Accepted ManuscriptDOI: 10.1039/D1DT02735B, CommunicationYang Zhang, Yakun Tang, Lang Liu, Yue Zhang, Zhiguo LiT-Nb2O5/CNT nanohybrid with short transmission path, rich active sites, and favorable mechanical flexibility can achieve the fast transportation of ions/electrons. The obtained nanohybrid with continuous conductive network...

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Efficient improvement in non-enzymatic glucose detection induced by the hollow prism-like NiCo2S4 electrocatalyst

Dalton Trans., 2021, Accepted ManuscriptDOI: 10.1039/D1DT02371C, PaperDandan Chu, Li Yan, Qiwen Chen, Xue-Qiang Chu, Danhua Ge, Xiaojun ChenThe hollow prism-like NiCo2S4 mateials (NiCo2S4 HNPs) were successfully fabricated by a two-step method. Scanning electron microscopy (SEM), transmission electron microscopy (TEM) and a powder X-ray diffraction...

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An Asymmetric Cryptand for the Site-Specific Coordination of 3d Metals in Multiple Oxidation States

Dalton Trans., 2021, Accepted ManuscriptDOI: 10.1039/D1DT02075G, PaperJulia Jökel, Frauke Nyßen, Daniel Siegmund, Ulf-Peter ApfelBis-tren (tren = tris(2-aminoethyl)amine) azacryptates were previously studied profoundly for the coordination of two +II metals and subsequent binding of substrates within their cavity. Likewise, cryptates including metals...

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A novel o-vanillin Fe(III) complex catalytically active in C–H oxidation: Exploring the magnetic exchange interactions and spectroscopic properties with different DFT functionals

Dalton Trans., 2021, Accepted ManuscriptDOI: 10.1039/D1DT02366G, PaperOksana V. Nesterova, Olga Vassilyeva, Brian W. Skelton, Alina Bieńko, Armando J. L. Pombeiro, Dmytro NesterovThe novel complex [FeIIICl(L)2(H2O)] (1) was synthesized by interaction of iron(III) chloride with ethanol solution of o-vanillin (HL) in air and characterized by IR, UV/Vis...

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The protonation state governs the coordination of phosphinoferrocene guanidines

Dalton Trans., 2021, Accepted ManuscriptDOI: 10.1039/D1DT02884G, PaperBarta Ondrej, Ivana Cisarova, Petr ŠtěpničkaCompared to phosphines with guanidinium tags, studied as polar ligands for aqueous catalysis, their counterparts bearing guanidine substituents received only limited attention. This contribution focuses on the coordination of phosphinoferrocene...The...

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CVD grown GaSbxN1-x films as visible-light active photoanodes

Dalton Trans., 2021, Accepted ManuscriptDOI: 10.1039/D1DT02455H, PaperDennis Zywitzki, Dariusz Mitoraj, Yury Vilk, Oliver Mendoza Reyes, Markus Schleuning, Dennis Friedrich, Alexander Sadlo, Detlef Rogalla, Rainer Eichberger, Radim Beranek, Anjana DeviThe III-V semiconductor GaN is a promising material for photoelectrochemical (PEC) cells, however the...

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Well-defined hollow tube@sheets NiCo2S4 core-shell nanoarrays for ultrahigh capacitance supercapacitor

Dalton Trans., 2021, Accepted ManuscriptDOI: 10.1039/D1DT02666F, PaperJiachao Zhou, Yingchao Wang, Jiaojiao Zhou, Kang Chen, Lei HanReasonable design of electrodes with well-defined nanostructure is the central aspects in the practical application of high-performance supercapacitors. Herein, hollow tube@sheets NiCo2S4 core-shell nanoarrays are rationally...

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