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RSC - Chem. Sci. latest articles

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The Driving Force for Co-translational Protein Folding is Weaker In the Ribosome Vestibule due to Greater Water Ordering

Chem. Sci., 2021, Accepted ManuscriptDOI: 10.1039/D1SC01008E, Edge Article Open Access   This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.Quyen V Vu, Yang Jiang, Mai Suan Li, Edward O'BrienInteractions between the ribosome and nascent chain can destabilize folded domains in the ribosome exit tunnel’s vestibule, the...

Turning Waste into Wealth: Facile and Green Synthesis of Graphene Nanodots from Pollutants and Applications to Bioimaging

Chem. Sci., 2021, Accepted ManuscriptDOI: 10.1039/D1SC02837E, Edge Article Open Access   This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Weifeng Chen, Jialu Shen, Zuo Wang, Yanyi Xu, Xiang Liu, Haiyu Zhao, Didier AstrucIn an effort to turn waste into wealth, Reactive Red 2 (RR2), a common and refractory...

Discovery and characterisation of an amidine-containing ribosomally-synthesised peptide that is widely distributed in nature

Chem. Sci., 2021, Accepted ManuscriptDOI: 10.1039/D1SC01456K, Edge Article Open Access   This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.Alicia H Russell, Natalia Miguel Vior, Edward Steven Hems, Rodney Lacret, Andrew William TrumanRibosomally synthesised and post-translationally modified peptides (RiPPs) are a structurally...

Me3SiSiMe2(OnBu): A Disilane Reagent for the Synthesis of Diverse Silacycles via Brook- and Retro-Brook-Type Rearrangement

Chem. Sci., 2021, Accepted ManuscriptDOI: 10.1039/D1SC03487A, Edge Article Open Access   This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Yankun Xu, Weiwei Xu, Xinyang Chen, Xiai Luo, Haiyan Lu, Minghao Zhang, Xiumei Yang, Guobo Deng, Yun Liang, Yuan YangHerein, the readily available disilane Me3SiSiMe2(OnBu)...

Coumarin luciferins and mutant luciferases for robust multi-component bioluminescence imaging

Chem. Sci., 2021, Advance ArticleDOI: 10.1039/D1SC03114G, Edge Article Open Access   This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Zi Yao, Donald R. Caldwell, Anna C. Love, Bethany Kolbaba-Kartchner, Jeremy H. Mills, Martin J. Schnermann, Jennifer A. PrescherNear-infrared probes were developed from...

On the limit of proton-coupled electronic doping in a Ti(IV)-containing MOF

Chem. Sci., 2021, Accepted ManuscriptDOI: 10.1039/D1SC03019A, Edge Article Open Access   This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Jenna L Mancuso, Kevin Fabrizio, Carl K. Brozek, Christopher H. HendonTiIV-containing metal-organic frameworks are known to accumulate electrons in their conduction...

‘Reverse biomimetic’ synthesis of L-arogenate and its stabilized analogues from L-tyrosine

Chem. Sci., 2021, Advance ArticleDOI: 10.1039/D1SC03554A, Edge Article Open Access   This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.Louise Eagling, Daniel J. Leonard, Maria Schwarz, Iñaki Urruzuno, Grace Boden, J. Steven Wailes, John W. Ward, Jonathan ClaydenL-Tyrosine provides a precursor for a practical synthesis...

Copper-catalyzed [3+1] cyclization of cyclopropenes/diazo compounds and bromodifluoroacetamides: facile synthesis of α,α-difluoro-β-lactam derivatives

Chem. Sci., 2021, Accepted ManuscriptDOI: 10.1039/D1SC02930D, Edge Article Open Access   This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Mengru Zhang, Hexin Li, Jinbo Zhao, Yan Li, Qian ZhangWe have developed a novel copper-catalyzed cyclization of cyclopropenes/diazo compounds and bromodifluoroacetamides,...

“Click-Switch” – one-step conversion of organic azides into photochromic diarylethenes for the generation of light-controlled systems

Chem. Sci., 2021, Accepted ManuscriptDOI: 10.1039/D1SC02526K, Edge Article Open Access   This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Steffy Becht, Reena Sen, Simon M. Bullmann, Andreas Dreuw, Andres JaeschkeDiarylethenes (DAEs) are an established class of photochromic molecules, but their effective...

Accelerating the insertion reactions of (NHC)Cu–H via remote ligand functionalization

Chem. Sci., 2021, Advance ArticleDOI: 10.1039/D1SC01911B, Edge Article Open Access   This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.Amy L. Speelman, Ba L. Tran, Jeremy D. Erickson, Monica Vasiliu, David A. Dixon, R. Morris BullockRemote modification of an N-heterocyclic carbene ligand with bulky or electron-rich groups...

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