RSC - Chem. Sci. latest articles

RSC - Chem. Sci. latest articles

Latest articles

C–H functionalization reactions enabled by hydrogen atom transfer to carbon-centered radicals

Chem. Sci., 2021, Advance ArticleDOI: 10.1039/D0SC04881J, Perspective Open Access   This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Sumon Sarkar, Kelvin Pak Shing Cheung, Vladimir GevorgyanIntramolecular and intermolecular HAT to C-centered radicals enables selective C–H functionalization of organic molecules.To...

Tri-insertion with Dearomatization of Terminal Arylalkynes at Carborane Based Frustrated Lewis Pair Template

Chem. Sci., 2021, Accepted ManuscriptDOI: 10.1039/D0SC05755J, Edge Article Open Access   This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Jian Zhang, Zuowei XieIntramolecular vicinal Frustrated Lewis Pairs (FLPs) have played a significant role in the activation of small molecules, and their stabilities...

A pyrone remodeling strategy to access diverse heterocycles: Application to the synthesis of fascaplysin natural products

Chem. Sci., 2021, Accepted ManuscriptDOI: 10.1039/D0SC06317G, Edge Article Open Access   This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Vignesh Palani, Melecio A. Perea, Kristen E. Gardner, Richmond SarpongThe synthesis of diverse N-fused heterocycles, including the pyrido[1,2-a]indole scaffold, using...

Consistent Inclusion of Continuum Solvation in Energy Decomposition Analysis: Theory and Application to Molecular CO2 Reduction Catalysts

Chem. Sci., 2021, Accepted ManuscriptDOI: 10.1039/D0SC05327A, Edge Article Open Access   This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.Yuezhi Mao, Matthias Loipersberger, Kareesa Kron, Jeffrey S. Derrick, Chris Chang, Shaama Mallikarjun Sharada, Martin Head-GordonTo facilitate computational investigation of intermolecular...

Supertetrahedral Polyanionic Network in the First Lithium Phosphidoindate Li 3 InP 2 - Structural Similarity to Li 2 SiP 2 and Li 2 GeP 2 and Dissimilarity to Li 3 AlP 2 and Li 3 GaP 2

Chem. Sci., 2021, Accepted ManuscriptDOI: 10.1039/D0SC05851C, Edge Article Open Access   This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.Tassilo M. F. Restle, Volker L. Deringer, Jan Meyer, Gabriele Raudaschl-Sieber, Thomas F FässlerPhosphide-based materials have been investigated as promising candidates for solid...

Carbon monoxide and hydrogen (syngas) as a C1-building block for selective catalytic methylation

Chem. Sci., 2021, Advance ArticleDOI: 10.1039/D0SC05404F, Edge Article Open Access   This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.Akash Kaithal, Markus Hölscher, Walter LeitnerA broadly applicable catalytic process for the selective β-methylation of alcohols is presented using syngas (CO/H2) directly as a C1 building...

Exploiting in-situ NMR to monitor the formation of a metal-organic framework

Chem. Sci., 2021, Accepted ManuscriptDOI: 10.1039/D0SC04892E, Edge Article Open Access   This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.Corey Leigh Jones, Colan E Hughes, Hamish Hei-Man Yeung, Alison Paul, Kenneth D M Harris, Timothy EasunThe formation processes of metal-organic frameworks are becoming more widely...

Cu-catalyzed hydroxycyclopropanol ring-opening cyclization to tetrahydrofurans and tetrahydropyrans: short total syntheses of hyperiones

Chem. Sci., 2021, Advance ArticleDOI: 10.1039/D0SC05556E, Edge Article Open Access   This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Weida Liang, Xinpei Cai, Mingji DaiA novel Cu-catalyzed hydroxycyclopropanol ring-opening cyclization was developed to synthesize substituted tetrahydrofuran/tetrahydropyran...

Total synthesis and complete configurational assignment of amphirionin-2

Chem. Sci., 2021, Accepted ManuscriptDOI: 10.1039/D0SC06021F, Edge Article Open Access   This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.Shota Kato, Daichi Mizukami, Tomoya Sugai, Masashi Tsuda, Haruhiko FuwaAmphirionin-2 is a linear polyketide metabolite that exhibits potent and selective cytotoxic activity against...

Organophosphorus-catalyzed relay oxidation of H-Bpin: electrophilic C–H borylation of heteroarenes

Chem. Sci., 2021, Advance ArticleDOI: 10.1039/D0SC05620K, Edge Article Open Access   This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.Jeffrey M. Lipshultz, Yue Fu, Peng Liu, Alexander T. RadosevichA nontrigonal phosphorus triamide (1, P{N[o-NMe-C6H4]2}) is shown to catalyze C–H borylation of electron-rich heteroarenes...

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