Influence of Linkers on the Kuratowski-type Secondary Building Unit in Nickel Single-site MOFs for Ethylene Oligomerization Catalysis: A Computational Study

Catal. Sci. Technol., 2021, Accepted ManuscriptDOI: 10.1039/D0CY02137G, PaperDaniela E. Ortega, Ricardo MatuteThe use of metal-organic frameworks (MOFs) as heterogeneous catalysts has been considered an efficient alternative for petrochemical and industrial applications. Ni-MFU-4l (dibenzodioxin-type backbone) and Ni-CFA-1 (biphenyl-type backbone) are...

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Regulating morphological and electronic structures of polymeric carbon nitrides by successive copolymerization and stream reforming for photocatalytic CO2 reduction

Catal. Sci. Technol., 2021, Accepted ManuscriptDOI: 10.1039/D0CY02293D, PaperRuirui Wang, Pengju Yang, Sibo Wang, Xinchen WangPolymeric carbon nitrides (PCNs) are attractive candidates for diverse photoredox catalysis, but the CO2 reduction activity of pristine PCNs is unsatisfactory, mainly due to the bulky structure and insufficient optical...The...

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Platinum and cobalt intermetallic nanoparticles confined within MIL-101(Cr) for enhanced selective hydrogenation of the carbonyl bond in α, β-unsaturated aldehydes: synergistic effects of electronically-modified Pt sites and Lewis acid sites

Catal. Sci. Technol., 2021, Accepted ManuscriptDOI: 10.1039/D0CY02082F, PaperMuhammad Zahid, Jiang Li, Ahmed Ismail, Francisco Zaera, Yujun ZhuPrecious metals have been shown to play a vital role in the selective hydrogenation of α, β-unsaturated aldehydes, but still suffer from challenges to control selectivity. Herein, we have advanced...The content...

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Synergetic effect of Cu active sites and oxygen vacancies in Cu/CeO2-ZrO2 for water-gas shift reaction

Catal. Sci. Technol., 2021, Accepted ManuscriptDOI: 10.1039/D0CY02462G, PaperYuanwu Hu, Na Wang, Zhiming ZhouA series of Cu/CeO2-ZrO2 catalysts with different Ce/(Ce+Zr) molar ratios and Cu loadings were prepared by a simple citrate sol-gel method, characterized by various techniques, and evaluated for water-gas shift...The content of this RSS Feed...

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Hierarchically porous magnetic Fe3O4/Fe-MOF used as effective platform for enzyme immobilization：kinetic and thermodynamic study on the structure-activity

Catal. Sci. Technol., 2021, Accepted ManuscriptDOI: 10.1039/D0CY02146F, PaperXia Gao, Quan-Guo Zhai, Mancheng Hu, Shuni Li, Yucheng JiangEnzymes are efficient catalysts offering much more competitive process compared with conventional chemical reaction. However, the lack of stability and reusability is a key issue on the implementation of enzymes...The...

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Copper (I) oxide nanoparticle-mediated C-C couplings for synthesis of polyphenylenediethynylenes: Evidence for homogeneous catalytic pathway

Catal. Sci. Technol., 2021, Accepted ManuscriptDOI: 10.1039/D1CY00039J, PaperFathima Pary, Ravi Teja Addanki Tirumala, Toby L. Nelson, Marimuthu AndiappanDuring the last few decades, substantial attention has been devoted to copper and copper oxide nanocatalysts since copper’s natural abundance, low cost and less toxic in comparison to precious-metal-based...

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A Combined Experimental and Computational Study to Decipher Complexity in the Asymmetric Hydrogenation of Imines with Ru Catalysts Bearing Atropisomerizable Ligands

Catal. Sci. Technol., 2021, Accepted ManuscriptDOI: 10.1039/D0CY02390F, Paper Open Access   This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Felix León, Aleix Comas-Vives, Eleuterio Alvarez González, Antonio PizzanoRuCl2(P-OP)(N-N) complexes (1) containing an atropisomerizable phophine-phosphite (P-OP)...

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Heterolytic Cleavage of Dihydrogen (HCD) in Metal Nanoparticle Catalysis

Catal. Sci. Technol., 2021, Accepted ManuscriptDOI: 10.1039/D0CY02399J, PerspectiveIsrael Cano, Luis Miguel Martínez-Prieto, Piet W. N. M. van LeeuwenThe heterolytic cleavage of H2 into H+ and H–, and the subsequent transfer of these hydrogen species to polarized C=X groups, is a useful strategy to obtain high selectivities in...The content of this...

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Synchrotron Infrared Spectroscopic High-Throughput Screening of Multi-composite Photocatalyst Films for Air Purification

Catal. Sci. Technol., 2021, Accepted ManuscriptDOI: 10.1039/D0CY02223C, CommunicationYuxue Wei, Azhu Wang, Lingling Lv, Faqiang Xu, Jie Yang, Mengdie Cai, Qin Cheng, Jingshuai Chen, Jun Bao, Chen Gao, Song SunCompared with conventional one-sample-at-a-time synthesis and characterization, combinatorial and high-throughput methods are effective strategies...

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Sunlight-promoted aerobic selective cyclization of olefinic amides and diselenides

Catal. Sci. Technol., 2021, Accepted ManuscriptDOI: 10.1039/D0CY02273J, PaperJiawei Hua, Mixue Bian, Tao Ma, Man Yang, Wei He, Zhao Yang, Chengkou Liu, Zheng Fang, Kai GuoA novel sunlight-promoted aerobic synthesis of selenation iminoisobenzofurans or isoindolinones via regioselective and chemoselective O-cyclization or N-cyclization of olefinic amides...

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