Converging conversion – using promiscuous biocatalysts for the cell-free synthesis of chemicals from heterogeneous biomass

Green Chem., 2021, Accepted ManuscriptDOI: 10.1039/D0GC04288A, PaperSamuel Sutiono, André Pick, Volker SieberProduction of chemicals from lignocellulosic biomass has been proposed as a suitable replacement to petrochemicals. However, one inherent challenge of biomass utilization is the heterogeneity of the substrate resulting in...The content of this...

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Eco-friendly Antisolvent Enabled Inverted MAPbI3 Perovskite Solar Cells with Fill Factors over 84%

Green Chem., 2021, Accepted ManuscriptDOI: 10.1039/D1GC00599E, PaperYuying Cui, Shurong Wang, Chengbo Li, Aili Wang, Jing Ren, Chenguang Yang, Bin Chen, Zhen Wang, Feng HaoAntisolvents assisted crystallization has been most widely applied in depositing high-quality perovskite thin films for efficient perovskite solar cells (PSCs). However, the toxicity...

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Oxo-functionalised Mesoionic NHC Nickel Complexes for Selective Electrocatalytic Reduction of CO2 to Formate

Green Chem., 2021, Accepted ManuscriptDOI: 10.1039/D1GC00388G, Paper Open Access   This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Simone Bertini, Motiar Rahaman, Abhijit Dutta, Philippe Schollhammer, Alexander V. Rudnev, Peter Broekmann, Frederic Gloaguen, Martin AlbrechtStrategies for the conversion...

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Hydroxyl group modified polymeric carbon nitride with highly selective hydrogenation of nitrobenzene to N-phenylhydroxylamine under visible light

Green Chem., 2021, Accepted ManuscriptDOI: 10.1039/D1GC00325A, Paper Open Access   This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.Linjuan Pei, Hao Tan, Meixian Liu, Ruiyi Wang, Xianmo Gu, Xuebin Ke, Jianfeng Jia, Zhanfeng ZhengRegulating the surface properties of catalysts to control the selectivity of reaction is...

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Transfer hydrogenation of high concentration levulinic acid to γ-valerolactone catalyzed by glucose phosphate carbamide zirconium

Green Chem., 2021, Accepted ManuscriptDOI: 10.1039/D1GC00209K, PaperFeifei Wan, Bo Yang, Jiekun Zhu, Dabo Jiang, Huanhuan Zhang, Suainan Chen, Qiao Zhang, Chao Zhang, Yachun Liu, Zaihui FuZr-based catalysts have been extensively applied in Meerwein–Ponndorf–Verley type of catalytic transfer hydrogenation (CTH) reactions, but they easily deactivate in...

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Catalyst-Free Photoinduced Selective Oxidative C(sp3)‒C(sp3) Bond Cleavage in Arylamines

Green Chem., 2021, Accepted ManuscriptDOI: 10.1039/D1GC00743B, CommunicationJingwei Zhou, Songping Wang, Wentao Duan, qi lian, Wentao WeiDue to the directional nature of sp3-hybridized orbitals and the absence of π-orbitals, the oxidative cleavage of the kinetically and thermodynamically stable C(sp3)‒C(sp3) bond is extremely difficult and remains scarcely...The...

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Chemo- and Regioselective Nucleophilic Hydrofunctionalization of Unactivated Aliphatic Alkenes under Transition-Metal-Free catalyst

Green Chem., 2021, Accepted ManuscriptDOI: 10.1039/D1GC00474C, CommunicationXiaojin Wu, ying zhan, Yao Zhao, Qiang Du, Jiacheng Rui, Rizhi Chen, Xintao ZhengA transition-metal-free-catalyzed nucleophilic hydrofunctionalization of both terminal and internal unactivated aliphatic alkenes has been firstly described. Most topical classes of carbon, nitrogen...

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Ring-Contraction of Hantzsch Ester and Derivatives to Pyrrole via Electrochemical Extrusion of Ethyl Acetate out of Aromatic Rings

Green Chem., 2021, Accepted ManuscriptDOI: 10.1039/D1GC00487E, PaperXu Liu, Liu Chang, Xu ChengAn electrochemical ring-contraction of HE and its derived pyridine is developed, giving polysubstituted pyrrole. This process provides an orthogonal utilization of Hantzsch ester to the well-documented application as side chain...The content of this RSS Feed...

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A review of thermal and thermocatalytic valorization of food waste

Green Chem., 2021, Accepted ManuscriptDOI: 10.1039/D1GC00536G, Critical ReviewElvis Osamudiamhen Ebikade, Sunitha Sadula, Yagya Gupta, Dion VlachosFood waste (FW) remains a global challenge due to the increasing demand for food production to support a growing global population and the lack of effective waste management technologies for...The content...

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C(sp3)–H Bond Functionalization with Styrenes via Hydrogen-Atom Transfer to an Aqueous Hydroxyl Radical under Photocatalysis

Green Chem., 2021, Accepted ManuscriptDOI: 10.1039/D1GC00753J, CommunicationShogo Mori, Susumu SaitoThe redox-neutral addition of α-C–H bonds of acetonitrile and acetone to styrenes was enabled via the hydrogen-atom transfer from relatively acidic and water-miscible C(sp3)–H bonds to an aqueous hydroxyl radical...The content of this RSS Feed (c) The...

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