Enantioselective Difunctionalization of Alkenes by a Palladium-Catalyzed Heck/Borylation Sequence

Chem. Sci., 2022, Accepted ManuscriptDOI: 10.1039/D1SC06229H, Edge Article Open Access   This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.Yuanqi Wu, Lizuo Wu, Zhanming Zhang, Bing Xu, Yu Liu, Junliang ZhangA palladium catalyzed enantioselective Heck/borylation reaction of alkene-tethered aryl iodides was realized, delivering...

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Salicylate Metal-Binding Isosteres as Fragments for Metalloenzyme Inhibition

Chem. Sci., 2022, Accepted ManuscriptDOI: 10.1039/D1SC06011B, Edge Article Open Access   This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.Moritz K Jackl, Hyeonglim Seo, Johannes Karges, Mark Kalaj, Seth M CohenMetalloenzyme inhibitors share a common need to possess a metal-binding pharmacophore (MBP) for binding the...

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Unveiling ultrafast dynamics in bridged bimetallic complexes using optical and X-ray transient absorption spectroscopies

Chem. Sci., 2022, Advance ArticleDOI: 10.1039/D1SC05034F, Edge Article Open Access   This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Michael W. Mara, Brian T. Phelan, Zhu-Lin Xie, Tae Wu Kim, Darren J. Hsu, Xiaolin Liu, Andrew J. S. Valentine, Pyosang Kim, Xiaosong Li, Shin-ichi Adachi, Tetsuo Katayama,...

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Construction of vicinal 4°/3°-carbons via reductive Cope rearrangement.

Chem. Sci., 2022, Accepted ManuscriptDOI: 10.1039/D1SC06307C, Edge Article Open Access   This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Kristin Sobie, Matthew Albritton, Yinuo Yang, Mariana Alves, Adrian E. Roitberg, Alexander GrenningHerein reported is a strategy for constructing vicinal 4°/3° carbons...

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Suzuki-type Cross-Coupling of Alkyl trifluoroborates with Acid Fluoride Enabled by NHC/Photoredox Dual Catalysis

Chem. Sci., 2022, Accepted ManuscriptDOI: 10.1039/D1SC06102J, Edge Article Open Access   This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Hua Huang, Qing-Song Dai, Hai-Jun Leng, Qing-Zhu Li, Si-Lin Yang, Ying-Mao Tao, Xiang Zhang, Ting Qi, Jun-Long LiThe Suzuki–Miyaura cross-coupling of C(sp3)-hybridised...

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How Well Does Molecular Simulation Reproduce Environment-Specific Conformations of the Intrinsically Disordered Peptides PLP, TP2 and ONEG?

Chem. Sci., 2022, Accepted ManuscriptDOI: 10.1039/D1SC03496K, Edge Article Open Access   This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.Lauren Reid, Ileana Guzzetti, Tor Svensson, Anna-Carin Carlsson, Wu Su, Tomas Leek, Lena von Sydow, Werngard Czechtizky, Marija Miljak, Chandra Verma, Leonardo De Maria, Jonathan...

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Enhancing the photothermal conversion of tetrathiafulvalene-based MOFs by redox doping and plasmon resonance

Chem. Sci., 2022, Advance ArticleDOI: 10.1039/D1SC07001K, Edge Article Open Access   This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Jian Su, Peiyu Cai, Tong Yan, Zhi-Mei Yang, Shuai Yuan, Jing-Lin Zuo, Hong-Cai ZhouThe photo-response of the redox-active metal–organic framework has been systematically...

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Site-Specific DNA Functionalization through the Tetrazene-Forming Reaction in Ionic Liquids

Chem. Sci., 2022, Accepted ManuscriptDOI: 10.1039/D1SC05204G, Edge Article Open Access   This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Jun Ohata, Seiya Ishizawa, Munkhtuya Tumurkhuu, Elizabeth J. GrossDevelopment of multiple chemical tools for deoxynucleic acid (DNA) labeling has facilitated wide use...

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A Different Polynorbornene Backbone by Combination of Two Polymer Growth Pathways: Vinylic Addition and Ring Opening via β-C Elimination

Chem. Sci., 2022, Accepted ManuscriptDOI: 10.1039/D1SC07028B, Edge Article Open Access   This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Ignacio Pérez-Ortega, Ana Carmen AlbenizA new polynorbornene skeleton has been found that contains bicyclic norbornane units and cyclohexenyl methyl linkages. The polymers...

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Principles of Melting in Hybrid Organic-Inorganic Perovskite and Polymorphic ABX3 Structures

Chem. Sci., 2022, Accepted ManuscriptDOI: 10.1039/D1SC07080K, Edge Article Open Access   This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.Bikash Kumar Shaw, Thomas Douglas Bennett, Celia Castillo Blas, Michael Francis Thorne, María Laura Ríos Gómez, Thomas Forrest, David A. Keen, Maria Diaz-Lopez, Philip A Chater,...

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