Polydopamine-based nanoreactors: synthesis and applications in bioscience and energy materials

Chem. Sci., 2020, Accepted ManuscriptDOI: 10.1039/D0SC04486E, Minireview Open Access   This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Shilin Mei, Xiaohui Xu, Rodney Dewayne Priestley, Yan LuPolydopamine (PDA)-based nanoreactors have demonstrated exceptional promise as multifunctional materials due to...

Oct 2020

Et3SiH + KOtBu Provide Multiple Reactive Intermediates that Compete in the Reactions and Rearrangements of Benzylnitriles and Indolenines

Chem. Sci., 2020, Accepted ManuscriptDOI: 10.1039/D0SC04244G, Edge Article Open Access   This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.Andrew J. Smith, Daniela Dimitrova, Jude N. Arokianathar, Kenneth F. Clark, Darren Poole, Stuart G. Leach, John MurphyThe combination of potassium tert-butoxide and triethylsilane...

Oct 2020

The Sporothriolides. A New Biosynthetic Family of Fungal Secondary Metabolites

Chem. Sci., 2020, Accepted ManuscriptDOI: 10.1039/D0SC04886K, Edge Article Open Access   This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Dongsong Tian, Eric Kuhnert, Jamal Ouazzani, Daniel Wibberg, Jorn Kalinowski, Russell CoxThe biosynthetic gene cluster of the antifungal metabolite sporothriolide 1...

Oct 2020

Ligand-protected gold/silver superatoms: current status and emerging trends

Chem. Sci., 2020, Accepted ManuscriptDOI: 10.1039/D0SC04100A, Perspective Open Access   This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Haru Hirai, Shun Ito, Shinjiro Takano, Kiichirou Koyasu, Tatsuya TsukudaMonolayer-protected gold/silver clusters have attracted much interest as nano-scale building units...

Oct 2020

Engineering of chiral nanomaterials for biomimetic catalysis

Chem. Sci., 2020, Accepted ManuscriptDOI: 10.1039/D0SC03245J, Perspective Open Access   This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.hongyu zhang, Aihua Qu, si li, changlong hao, Maozhong Sun, Liguang Xu, Chuanlai Xu, Hua KuangThe chiral nanomaterials-based biomimetic catalysts can trigger similar...

Oct 2020

Cooperative activating effects of metal ion and Brønsted acid on a metal oxo species

Chem. Sci., 2020, Accepted ManuscriptDOI: 10.1039/D0SC04069J, Edge Article Open Access   This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Gui Chen, Li Ma, Po Kam Lo, Chi Keung Mak, Kai Chung LAU, Tai-Chu LauMetal oxo (M=O) complexes are common oxidants in chemical and biological systems. The use of Lewis...

Oct 2020

Ultrasensitive small molecule fluorogenic probe for human heparanase

Chem. Sci., 2020, Accepted ManuscriptDOI: 10.1039/D0SC04872K, Edge Article Open Access   This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Jun Liu, Kelton A Schleyer, Tyrel L. Bryan, Changjian Xie, Gustavo Seabra, Yongmei Xu, Arjun Kafle, Chao Cui, Ying Wang, Kunlun Yin, Benjamin Fetrow, Paul KP Henderson,...

Oct 2020

Direct synthesis of the organic and Ge free Al containing BOG zeolite (ITQ-47) and its application for transformation of biomass derived molecules

Chem. Sci., 2020, Advance ArticleDOI: 10.1039/D0SC04044D, Edge Article Open Access   This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Qintong Huang, Ningyue Chen, Lichen Liu, Karen S. Arias, Sara Iborra, Xianfeng Yi, Chao Ma, Weichi Liang, Anmin Zheng, Chuanqi Zhang, Jibo Hu, Zilin Cai, Yi Liu, Jiuxing...

Oct 2020

Identifying reactive intermediates by mass spectrometry

Chem. Sci., 2020, Accepted ManuscriptDOI: 10.1039/D0SC04754F, Perspective Open Access   This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.Jaya Mehara, Jana RoithovaDevelopment of new reactions requires finding and understanding of novel reaction pathways. In challenging reactions such as C-H activations, these pathways...

Oct 2020

A Case of Chain Propagation: α-Aminoalkyl Radicals as Initiators for Aryl Radical Chemistry

Chem. Sci., 2020, Accepted ManuscriptDOI: 10.1039/D0SC04387G, Edge Article Open Access   This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Timothée Constantin, Fabio Juliá, Nadeem Sheikh, Daniele LeonoriThe generation of aryl radicals from the corresponding halides by redox chemistry is generally considered...

Oct 2020