Wiley Online Library : ChemCatChem
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Organo‐Soluble Colloidal MoS2 Quantum Dots (QDs) as an Efficient Photocatalyst for α‐Amino Phosphonate Synthesis

α-Amino phosphonates are bio-isosteres of amino acids and have numerous biochemical activities. While they are generally prepared via carbon–phosphorus bond formation using a plethora of methods but using recyclable photo-catalysts and readily accessible amine and phosphites are not commonly used in synthesis. Herein, we used organo-soluble MoS2 Quantum...

Thu Apr 25, 2024 13:40
PdSnW Ternary Alloy Nanoparticle with Excellent CO Anti‐poisoning Activity for Boosting Alkaline Ethanol Oxidation Reaction

Efficient ethanol oxidation reaction (EOR) catalysts with anti-poisoning ability and high selectivity are in high demand for the widespread application of direct ethanol fuel cells (DEFCs). Here, the PdSnW ternary alloy nanoparticles are synthesized by a facile solvothermal method and exhibit an enhanced EOR catalytic performance. CO stripping experiment,...

Thu Apr 25, 2024 13:40
Economically competitive Organic Acid‐Base mixtures as Catalysts for the Self‐Condensation of Diols into Polyethers

Organocatalysts are used in a wide range of polymerisation reactions with the advantage of being often more benign or sustainable, while maintaining high catalytic activity. However, the low thermal stability of most of these compounds remain an obstacle for high temperature reactions. It was recently reported that complexes formed from a base such...

Thu Apr 25, 2024 13:40
Achieving Regioselective Control for Mechanochemical Reactions: A Planetary Ball‐Milling, Ru‐Catalyzed Synthesis of 3,4‐ and 3,4,5‐Isoxazoles.

A mechanochemical-enabled Ru-catalyzed regioselective synthesis of 3,4-isoxazoles and 3,4,5-isoxazoles from terminal and internal alkynes and hydroxyimidoyl chlorides is reported. This solid-state and solvent-free approach carefully examines the impact of the milling conditions on regiocontrol in 1,3-dipolar cycloadditions using mechanochemical means....

Thu Apr 25, 2024 13:40
Cover Feature: Ionic liquid templated synthesis of cobalt‐substituted mesoporous aluminophosphates: A novel heterogeneous catalyst for selective oxidation of cyclohexane to cyclohexanol (ChemCatChem 8/2024)

The Cover Feature showcases the creation of an ordered hexagonal mesoporous cobalt aluminophosphate, viz., CoMAP-41, using an ionic liquid such as HDmimCl as a structure-directing agent. In their Research Article, H. Manyar, P. Selvam et al. describe the HDmimCl-based CoMAP-41 that boasts thicker pore walls, conferring an improved structural stability,...

Wed Apr 24, 2024 13:26

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