Wiley Online Library : Chemistry - A European Journal
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Advanced Synthesis, Structural Characterization, and Functional Applications of Precision Polymers

By synthesizing precision polymers using four methods – solid-phase synthesis, liquid-phase synthesis, DNA-template synthesis, and controlled polymerization – precision polymers with special properties in thermodynamics and crystalline performance have been achieved. These polymers play important roles in fields such as self-assembly, catalysis, data...

Fri Sep 20, 2024 11:02
Sulfonamide‐Sulfonimide Copolymers as Novel, Fluorine‐Lean Type of Proton Exchange Membranes for Fuel Cell Application

In the ongoing search for a cheap and fluorine-free alternative for perfluorinated sulfonic acid-polymers (PFSAs), we investigate a set of novel copolymers combining sulfonamide and sulfonimide functionalities. The materials show outstanding conductivities of up to 283 mS c−1, high thermal stability over 250 °C and easy manufacturing. On top they...

Fri Sep 20, 2024 11:02
In situ Reconstructured Alloy Nanosheets Heterojunction for Highly Selective Electrochemical CO2 Reduction to Formate

An in-situ reconstruction process fabricates the Cu2O@Cu6Sn5 heterojunction while preserving the two-dimensional morphology. The synergistic effect of Cu and Sn active sites stabilizes the *OCHO intermediate, thereby facilitating efficient electrocatalytic formate production. The designed Cu2O@Cu6Sn5 heterojunction demonstrates outstanding CO2RR performance,...

Fri Sep 20, 2024 11:02
An Effective Strategy on Synthesizing a Stable SiOx‐Based Anode for High Density Lithium‐Ion Batteries

Lithium fluoride (LiF) serves as a modified additive, which can enhance the electrochemical performance in SiOx anode material in lithium-ion batteries. Here, we demonstrate a simple way to prepare a series of SiOx materials with LiF modified. The addition of LiF can stabilize the solid electrolyte interphase layer, reduce the volume expansion, and...

Fri Sep 20, 2024 11:02
Bipyramidal Nanocrystals of Noble Metals: From Synthesis to Applications

This review covers bipyramidal nanocrystals of noble metals, with a focus on the roles played by reduction, etching, and capping in their nucleation and growth. It also discusses how to control the exposed facets, size, aspect ratio, and corner truncation, as well as their effects on plasmonic properties and catalytic applications. Abstract...

Fri Sep 20, 2024 11:02
Benzodifuranone Crystals with Solid‐State Emission Arising from the Introduction of Bulky Substituents

We achieved benzodifuranone crystals with unprecedented solid-state emission achieved through the introduction of bulky aromatic groups. In addition to the unprecedented solid-state emission, the compound showed luminescent mechanochromism and thermosalient effect. Abstract Benzodifuranone derivatives, structural analogues of widely studied...

Fri Sep 20, 2024 11:02

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