Wiley Online Library : Advanced Energy Materials
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Homogeneous In‐Plane Lattice Strain Enabling d‐Band Center Modulation and Efficient d–π Interaction for an Ag2Mo2O7 Cathode Catalyst With Ultralong Cycle Life in Li‐O2 Batteries

The homogeneous in-plane distortion of Ag2Mo2O7 leads to d-band center optimization and the spatial and energy overlap of Ag dxz and O2 anti-bonding π* orbitals, achieving highly efficient catalytic activity and rapid ORR/OER kinetics with an ultralong cycle life of 817 cycles at a current density of 500 mA g‒1 in LOBs. Abstract Although...

Sat Jun 15, 2024 11:37
Ternary Metal Sulfides as Electrode Materials for Na/K‐Ion Batteries and Electrochemical Supercapacitor: Advances/Challenges and Prospects

Ternary metal sulfides (TMSs) show potential as electrode materials for rechargeable batteries and supercapacitors (SCs). However, their real-world application faces challenges. This review discusses strategies for enhancing electrochemical activity through tailored nanostructures, backed by a comprehensive literature survey of recent advancements....

Sat Jun 15, 2024 11:37
Thickness Insensitive Organic Solar Cells with High Figure‐of‐Merit‐X Enabled by Simultaneous D/A Interpenetration and Stratification

By sequential deposition of using poor solvent to treat bottom polymer donor layer, an outstanding figure-of-merit-X (low-cost and thick-film) organic solar cell is realized. The underlying mechanism is carefully characterized as a interpenetrating and vertical stratified donor–acceptor structure, where donor layer's thickness is the key factor. ...

Sat Jun 15, 2024 11:37
A Hydridoaluminate Additive Producing a Protective Coating on Ni‐Rich Cathode Materials in Lithium‐Ion Batteries

An Al-based reducing agent lithium tri-tert-butoxy hydridoaluminate (LTBA) proposed as an electrolyte additive forms in-situ an Al-rich surface layer on Ni-rich layered oxides. This protective layer reduces interfacial reactivity and improve stability, resulting in ≈90% capacity retention after 240 cycles (vs Li4Ti5O12) compared to only 68% without...

Wed Jun 12, 2024 21:20
Prospects and Strategies for Single‐Crystal NCM Materials to Solve All‐Solid‐State Battery Cathode Interface Problems

This article starts with the advantages and disadvantages of all-solid-state battery electrolyte cathode materials and summarizes the advantages and challenges of single-crystal cathodes in solving all-solid-state battery interface problems. The impact of single-crystal cathode morphology on the design of high-performance all-solid-state batteries...

Wed Jun 12, 2024 21:20
Exploiting the Mixed Entropy Strategy for the Design of Fast Ion Conductors

This is the first time to report the relationship between mixed entropy and ion transport in electrolytes with different mixed entropy. Combining thermodynamic mixed entropy with ion transport kinetics and applying the atomic-level microstructure entropy concept in solid electrolyte design provides new insights into the design and development of solid-state...

Wed Jun 12, 2024 21:20

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