Thermally stimulated cascade reaction polymer membranes: a promising strategy for an increased hydrogen and propylene purification performance

Polym. Chem., 2023, 14,547-561DOI: 10.1039/D2PY00712F, PaperDavid Meis, Silvio Neumann, Sergey Shishatskiy, Ulrike Meis, Volkan FilizA thermally stimulated cascade of reactions in solid-state of tailored polyimides was developed with the aim of lowering the target temperature for the final reaction step towards a polybenzoxazole and improvement of the...

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Understanding the Monomer Deuteration Effect on the Transition Temperature of poly(N-isopropylacrylamide) Microgels in H2O

Polym. Chem., 2023, Accepted ManuscriptDOI: 10.1039/D2PY01511K, PaperThomas Nevolianis, Andrea Scotti, Alexander V. Petrunin, Walter Richtering, Kai LeonhardObtaining deuterated micro- and nanogels is essential to characterize their architecture and determine their response to crowding using neutron scattering with contrast variation. Experimental studies...

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Low Birefringence, Low Dispersion Aliphatic Thermosets with High and Tunable Refractive Index

Polym. Chem., 2023, Accepted ManuscriptDOI: 10.1039/D2PY01327D, PaperYujin Jeon, Ji Sung Choi, Donghwa Seo, Soon Hwa Jung, Jeewoo LimWe herein present a new class of high refractive index polymers prepared through the reaction of bis(2,3-epithiopropyl)sulfide, a series of poly(alkyl polysulfide)s, and elemental sulfur. The addition of an amine...The...

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Palladium-Catalyzed synthesis of oil-based functionalized polyolefin

Polym. Chem., 2023, Accepted ManuscriptDOI: 10.1039/D3PY00012E, PaperJiawei Chen, Wenbing Wang, Yao Pan, Dan Peng, You-Gui Li, Chen ZouThe fabrication of functionalized polyolefin materials from renewable biomasses is of great importance for sustainable development. In this study, we achieved direct copolymerization of plant oil-based copolymer monomers...

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Control of Microphase-separated Structures by Tuning the Functional Groups and the Degree of Modification for a Single Block Copolymer

Polym. Chem., 2023, Accepted ManuscriptDOI: 10.1039/D2PY01435A, PaperZhengdan Lin, Yuta Nabae, Teruaki HayakawaTo control the self-assembed morphology of block copolymers (BCPs), a series of BCPs was synthesized and post-functionalized via click chemistry. More specifically, polystyrene-b-poly(allyl glycidyl ether)s (PS-b-PAGEs) were synthesized via...

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Dual crosslinking polymer networks: correlation between polymer topologies and self-healing efficiency

Polym. Chem., 2023, Advance ArticleDOI: 10.1039/D3PY00025G, PaperSoonyoung Choi, Junhee Kim, Eunyong Seo, Hyocheol Jung, Ji-Eun Jeong, Young Il Park, Jin Chul Kim, Dong Woog Lee, Byeong-Su Kim, Sang-Ho LeeWe investigated the effect of polymer topologies on the efficiency of self-healing in polymer networks containing B-O bonds.To cite this article before...

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Terpenes as natural building blocks for the synthesis of hierarchically porous polymers: Bio-based polyHIPEs with high surface areas

Polym. Chem., 2023, Accepted ManuscriptDOI: 10.1039/D2PY01566H, Paper Open Access   This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.Stanko Kramer, Nika Skušek, Peter KrajncPolyHIPEs are hierarchically porous polymers which are generally synthesised from synthetic constituents produced from fossil fuels. The need to...

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Effect of Amino Group Modification at Allyl Position of Methacrylamides on Polymerization and Polymer pH-/Thermo-Responsiveness

Polym. Chem., 2023, Accepted ManuscriptDOI: 10.1039/D2PY01611G, PaperYasuhiro Kohsaka, Nyamdolgor Chinbat, Keiichiro Ito, Yosuke AkaeFor the interest in β-amino acid derivative polymers containing carbon backbone, the polymerization of N-n-propyl α-(aminomethyl)acrylamide (4b) and N-isopropyl α-(aminomethyl)acrylamide (4b) were investigated. The synthesis...

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An efficient cyclodepolymerization route for chemical recycling of poly(ethylene adipate)

Polym. Chem., 2023, Accepted ManuscriptDOI: 10.1039/D2PY01613C, PaperHongjuan Li, Xiangxiang Yan, Jie Huan, Sheng Wang, Xiaohong Li, Yatao Wang, Yingfeng Tu, Zhiping LiCyclodepolymerization is a special chemical recycling (upcycling) method for polyesters based on the ring-chain equilibria in solution, yet it is usually carried out in halogenated solvents...

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Glaser coupling for the synthesis of transformable polymacrocyclic polymers

Polym. Chem., 2023, Accepted ManuscriptDOI: 10.1039/D3PY00002H, PaperJinghang Wang, Chaofan Zhou, Hewen LiuFollowing the success in the synthetic methodology of macrocyclic polymers, effective construction of the precise structures of polymacrocyclic polymers with macrocyclic repeating units have been new pursuits in the fields...The content of this...

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