Wiley Online Library : Chemistry – An Asian Journal
2k followers 45 articles/week
Highly Stretchable Polyurethane Porous Membranes with Adjustable Morphology for Advanced Lithium Metal Batteries

A series of PU membranes with tunable microstructure are fabricated and employed in lithium metal based battery for the first time. The spongy-like morphology with high density of ultrasmall pores on the surface can physically induce the genuine deposition of the lithium metal on the electrode. In addition, the good lithiophilicity of the NH/O atoms...

Tue May 21, 2024 12:28
COAP‐Pd Catalyzed Asymmetric Formal [3+2] Cycloaddition for Optically Active Multistereogenic Spiro Cyclopentane‐Indandiones Bearing Cyclic N‐Sulfonyl Ketimine Skeletons

We reported a chiral oxamide-phosphine ligand (COAP−Ph)-Pd-catalyzed asymmetric formal [3+2] cycloaddition reaction between indane-1,3-dione-2-spirovinylcyclopropane and 2-vinylcyclopropane-1,1-dicarboxylates with cyclic sulfonyl 1-azadienes, which respectively delivered an array of enantio-enriched spiro cyclopentane-indandiones and cyclopentane...

Tue May 21, 2024 12:28
Dual‐stimuli‐responsive Turn‐on Luminescence of Chiral Bisimidazolyl BINOL Dimethyl Ether Crystals

Stimuli-responsive organic luminescent crystals have attracted significant attention in recent years for their potential in sensor and memory applications. While turn-on luminescence is superior in detection sensitivity compared with turn-off luminescence, the development of organic crystals that exhibit turn-on luminescence in response to multiple...

Tue May 21, 2024 12:28
Synthesis and Characterization of Bulky 1,3‐Diamidopropane Complexes of Group 2 Metals (Be ‒ Sr)

Reaction of lithium 1,3-diamidopropane Li2(TripNCN) (TripNCN = [{(Trip)NCH2}2CH2]2-, Trip = 2,4,6-triisopropylphenyl) with BeBr2(OEt2)2 gave the diamido beryllium complex, [(TripNCN)Be(OEt2)]. Deprotonation reactions between the bulkier 1,3-diaminopropane (TCHPNCN)H2 (TCHPNCN = [{(TCHP)NCH2}2CH2]2-, TCHP = 2,4,6-tricyclohexylphenyl) and magnesium alkyls...

Sun May 19, 2024 12:43
Synthesis and Characterization of Bulky 1,3‐Diamidopropane Complexes of Group 2 Metals (Be ‒ Sr)

Reaction of lithium 1,3-diamidopropane Li2(TripNCN) (TripNCN = [{(Trip)NCH2}2CH2]2-, Trip = 2,4,6-triisopropylphenyl) with BeBr2(OEt2)2 gave the diamido beryllium complex, [(TripNCN)Be(OEt2)]. Deprotonation reactions between the bulkier 1,3-diaminopropane (TCHPNCN)H2 (TCHPNCN = [{(TCHP)NCH2}2CH2]2-, TCHP = 2,4,6-tricyclohexylphenyl) and magnesium alkyls...

Sat May 18, 2024 11:53
Homogeneous and Heterogeneous Frustrated Lewis Pairs for the Activation and Transformation of CO2

This article reviews the utilization of Frustrated Lewis pairs (FLPs) including the homogeneous and heterogeneous FLPs for activating and transforming CO2. Lewis acids as electron acceptors cooperate with Lewis bases as electron donors to interact with CO2, leading to the formation of FLP-CO2 adducts and further converting CO2 into valuable chemicals....

Sat May 18, 2024 11:53

Build your own newsfeed

Ready to give it a go?
Start a 14-day trial, no credit card required.

Create account