Enhanced 5f-δ bonding in [U(C7H7)2]−: Carbon K‑Edge X‑ray Spectroscopy, Magnetism and Electronic Structure Calculations

Chem. Commun., 2021, Accepted ManuscriptDOI: 10.1039/D1CC03414F, CommunicationYusen Qiao, Gaurab Ganguly, Corwin H. Booth, Jacob Branson, Alex Ditter, Daniel Lussier, Liane Moreau, Dominic R. Russo, Dumitru-Claudiu SERGENTU, David K Shuh, Taoxiang Sun, Jochen Autschbach, Stefan Minasian[U(C7H7)2]− is a singular molecule, as the only η7-cycloheptatrienyl...

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Green synthesis of silver indium telluride nanocrystals: characterization and photothermal analysis

Chem. Commun., 2021, Accepted ManuscriptDOI: 10.1039/D1CC03111B, CommunicationFelipe Leon Nascimento Sousa, Brenand Anjos Santos Souza, Anderson Caires, Severino Alves Junior, Denilson Vasconcelos Freitas, Marcelo NavarroHere, we report the preparation and characterization of stable AgIn5Te8 (AITe) nanocrystals (NCs) and respective AITe-ZnS and AITe-ZnSe...

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Strain-release C-C bond cleavage enables the [2,3]-sigmatropic rearrangement of tertiary allylamines

Chem. Commun., 2021, Accepted ManuscriptDOI: 10.1039/D1CC03141D, CommunicationRui-Han Dai, Lu Han, Qi Wang, Shi-Kai TianA new strategy has been established for the [2,3]-sigmatropic rearrangement of quaternary allylammonium ylides, generated in situ from tertiary allylamines and a bicyclo[1.1.0]butane via strain-release C-C bond cleavage. A range...The...

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K2S2O8 activation by glucose at room temperature for synthesis and functionalization of heterocycles in water

Chem. Commun., 2021, Accepted ManuscriptDOI: 10.1039/D1CC03777C, CommunicationJoydev K. Laha, Mandeep Kaur HunjanWhile persulfate activation at room temperature using glucose is primarily focused on kinetic studies of sulfate radical anion, utilization of this protocol in organic synthesis is rarely demonstrated. We reinvestigated...The content of...

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Dynamics of a [2]rotaxane wheel in a crystalline molecular solid

Chem. Commun., 2021, Advance ArticleDOI: 10.1039/D1CC03009D, CommunicationGiorgio Baggi, Benjamin H. Wilson, Ayan Dhara, Christopher, A. O’Keefe, Robert W. Schurko, Stephen J. LoebA highly crystalline material comprised of [2]rotaxanes shows large amplitude motion of the interlocked macrocycle as evidenced by variable-temperature (VT) 2H solid-state...

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Visible-light Induced Photo-Click and Release Strategy between Monoarylsydnone and Phenoxylfumarate

Chem. Commun., 2021, Accepted ManuscriptDOI: 10.1039/D1CC02841C, CommunicationHui Liu, Tingting Zheng, Yuanqin Zheng, Bao-Lin Li, Xinyu Xie, Xin Shen, Xiaohu Zhao, Zhipeng YuWe report a visible-light induced photo-click and release platform between monoarylsydnone (MASyd) and phenoxylfumarates. The pyrazoline produced by the cycloaddition undergoes...

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High loading of Mn(II)-metalated porphyrin in MOF for photocatalytic CO2 reduction in gas−solid condition

Chem. Commun., 2021, Accepted ManuscriptDOI: 10.1039/D1CC02847B, CommunicationJian-Hua Qin, Peng Xu, Ya-Dan Huang, Lu-Yao Xiao, Weiwei Lu, Xiao-Gang Yang, Lufang Ma, Shuang-Quan ZangA high loading of Mn(II)-metalated porphyrin was achievable in a 2D porphyrin-based Mn-MOF induced by an ionic liquid. The excellent stability, sufficient redox potential,...

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Collaboratively boosting charge transfer and CO2 chemisorption of SnO2 to selectively reduce CO2 to HCOOH

Chem. Commun., 2021, Accepted ManuscriptDOI: 10.1039/D1CC01818C, CommunicationYusheng Yuan, Kai Sheng, Gui-lin Zhuang, Qiu-Yan Li, Cong Dou, Qiao-Jun Fang, Wenwen Zhan, Hao Gao, Di Sun, Xi-Guang HanIn this paper, we have facilely developed a SnO2-based electrocatalyst (SnO2-VO@N-C), which can combine together the favorable structure features of oxygen...

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Mn3MnNb2O9: high pressure triple perovskite with 1:2 B-site order and modulated spins.

Chem. Commun., 2021, Accepted ManuscriptDOI: 10.1039/D1CC02782D, CommunicationElena Solana-Madruga, Clemens Ritter, Cintli Aguilar, Olivier Mentré, Paul Attfield, Angel M. Arevalo-LopezThe first triple perovskite with Mn in A- and 1:2 B-site order Mn3MnNb2O9, prepared by high pressure phase transformation of the magnetodielectric Mn4Nb2O9, is reported...

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Sequential [3+2] annulation reaction of prop-2-ynylsulfonium salts and hydrazonyl chlorides: synthesis of pyrazoles containing functional motifs

Chem. Commun., 2021, Accepted ManuscriptDOI: 10.1039/D1CC02735B, CommunicationTao Shi, Zhaoxiao Wu, Tingting Jia, Chong Zhang, Linghui Zeng, Rangxiao Zhuang, Jiankang Zhang, Shourong Liu, Jiaan Shao, Huajian ZhuA novel sequential [3+2] annulation reaction has been developed using prop-2-ynylsulfonium salts and hydrazonyl chlorides, affording a series...

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