Org. Chem. Front., 2024, Accepted Manuscript DOI: 10.1039/D4QO00444B, Research ArticleJiang-Chun Wei, Pingping Fan, Yahui Huang, Hanxiao Zeng, Rui Jiang, Zhengzhi Wu, Zhengxi Hu, Yonghui Zhang (±)-Hypandrone A (1), a pair of highly modified polycyclic polyprenylated acylphloroglucinol (PPAP) enantiomers, with an unprecedentedly caged 2,8,17-trioxapentacyclo-[11.4.2.01,9.04,9.010,15]-nonadecane...

Org. Chem. Front., 2024, Accepted Manuscript DOI: 10.1039/D4QO00332B, Research ArticleJia-Lan Zhang, Jin-Xiu Xiong, Lu-Qi Fei, Fei-Hu Cui, Shu-Hui Li, Hai-Tao Tang, Yan-Zhao Xie, Ying-Ming Pan Fluoroalkylated allenes are potential compounds for drug and material development. Herein, we report electrochemical-mediated trifluoromethylallenes synthesis...

Org. Chem. Front., 2024, Accepted Manuscript DOI: 10.1039/D4QO00508B, Research ArticleRui Chen, Cong Lu, Yujun Li, Ke Zheng Deuterated α-tertiary amino acids serve as crucial constituents in the synthesis of deuterated pharmaceuticals and find utility in various biologically relevant compounds. Herein, we present a redox-neutral strategy for Markovnikov......

Org. Chem. Front., 2024, Accepted Manuscript DOI: 10.1039/D4QO00426D, Research ArticleYang Xu, Yinong Wu, Xufeng Lin A highly diastereoselective organophotoredox-catalyzed [3 + 2] cycloaddition of N-aryl cyclopropylamines with N-vinylphthalimides was reported. This transformation leads to diverse cis-cyclopentane-1,2-diamine derivatives via a dual catalyst...

Org. Chem. Front., 2024, Accepted Manuscript DOI: 10.1039/D4QO00401A, Research ArticleJian Luo, Mengchu Zhang, Gengxin Liu, Zhonghui Zhang, Yu Qian, Wenhao Hu Herein, we report a multifunctionalization reaction of Rh-carbynoids with alcohols/carbamates and α-propargylic-3-indolymethanols through trapping of di-heteroatom ylides with carbocation via...

Org. Chem. Front., 2024, Accepted Manuscript DOI: 10.1039/D4QO00504J, Research ArticleXin Peng, Huanliang Hong, Li Wang, Lu Chen, Jin-Bao Peng, Yibiao Li, Huanfeng Jiang Controlling the selectivity of reactions of palladium catalysts with various substrates is challenging. Herein, a general and unprecedented Pd-catalysed four-component inter-molecular...