RSC - Org. Chem. Front. latest articles
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Dual Photoredox/Nickel-Catalyzed Mizoroki-Heck Cross-Coupling Reactions

Org. Chem. Front., 2024, Accepted Manuscript DOI: 10.1039/D4QO00572D, Research ArticleJun Dong, Yanfei Hu, Yan Tang, Fen Zhao, Yongyun Zhou, Baomin Fan A method for the Mizoroki-Heck reaction of electron-deficient olefins acrylates with commercially available aryl bromides to obtaining α-arylation products of acrylates via dual light/nickel catalytic...

Fri Apr 26, 2024 06:49
Palladium/copper-cocatalyzed three-component tandem cyclization of o-alkenyl arylisocyanides, sulfur ylides with alcohols: direct synthesis of spiro 3,3’-cyclopropyl oxindoles

Org. Chem. Front., 2024, Accepted Manuscript DOI: 10.1039/D4QO00560K, Research ArticleYue Gong, Xue-Cen Xu, Zi-Xuan Yang, Yu-Long Zhao A novel palladium/copper-cocatalyzed three-component tandem cyclization of o-alkenyl arylisocyanides, sulfur ylides with alcohols has been developed for the first time. The reaction provides a simple and efficient method...

Fri Apr 26, 2024 06:49
Ring Expansion of Unsubstituted Aziridinium Ylide to Trifluoromethylated Dehydropiperidines

Org. Chem. Front., 2024, Accepted Manuscript DOI: 10.1039/D4QO00537F, Research ArticleYongquan Ning, Jiaqi Tang, Tian Tian, Yingyu Wang, Dandan Wei, Yong Yang, Xin-Yu Wang, Paramasivam Sivaguru, Zhaohong Liu, Valentine Nenajdenko The first rhodium-catalyzed [3+3] ring expansion of unsubstituted aziridines was achieved using trifluoroalkenyl N-triftosylhydrazones...

Wed Apr 24, 2024 12:46
Synthesis and anion recognition characteristics of a trapezoidal benzene cage

Org. Chem. Front., 2024, Accepted Manuscript DOI: 10.1039/D4QO00699B, Research ArticleCaihong Mao, Ruiye Wu, Nana Chen, Hanliang Zheng, Yan Cai, Lichun Kong, Xiaobo Hu The molecular recognition pockets of functional biomacromolecules typically have complex spatial geometries. Creating low symmetrical cage molecules, which are different from traditional...

Wed Apr 24, 2024 06:45
NHC-Catalyzed Stereoselective Synthesis of Spirooxindole Lactones by in situ Generated Oxindole-embedded o-Quinone Methides and Aldehydes

Org. Chem. Front., 2024, Accepted Manuscript DOI: 10.1039/D4QO00347K, Research ArticleZhengqiang Cao, Fang Hu, Yunpeng Chu, Jiaxue Pei, Xin-Ping Hui A novel N-heterocyclic carbene-catalyzed asymmetric [4 + 2] annulation of in situ generated oxindole-embedded o-quinone methides with aldehydes has been developed for the assembly of complicated spirooxindoles....

Mon Apr 22, 2024 22:06
Catalytic Ortho C-H Methylation and Trideuteromethylation of Arylthianthrenium Salts via the Catellani Strategy

Org. Chem. Front., 2024, Accepted Manuscript DOI: 10.1039/D4QO00506F, Research ArticleChen Chen, Xiao-Xu Zhang, Zi-Yi Wang, Chunjie Ni, Bolin Zhu We reported a Pd/NBE cooperative catalyzed ortho C−H methylation and trideuteromethylation of arylthianthrenium salts, enabling the efficient synthesis of a wide variety of (trideutero)methylated arenes in...

Mon Apr 22, 2024 19:06

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