Wiley Online Library : Macromolecular Theory and Simulations
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Swelling Behaviors of Natural Rubber/Solvent Systems Based on the Extended Modified Double Lattice Model

Abstract Swelling experiments were conducted on non-filler natural rubber (NR) using four solvents (toluene, cyclohexane, tetrahydrofuran (THF), and methylethylketone (MEK)) over temperatures from 10 to 70 °C. Toluene, cyclohexane, and THF, classified as effective solvents, showed swelling ratios between 3 and 7, influenced by the crosslink density...

Fri Apr 19, 2024 11:45
Numerical Analysis of the Blade Coating Process Using Non‐Newtonian Nanofluid with Magnetohydrodynamic (MHD) and Slip Effects

Abstract The coating process is widely used in various industries to enhance the production quality and efficiency. This study gives a comprehensive analysis of non-isothermal blade coating of non-Newtonian nanofluid incorporating magnetic, thermophoresis, and Brownian effects. The Mathematical equations derived from mass, momentum, and energy conservation...

Thu Apr 18, 2024 11:54
Quantitative Structure‐Property Relations for Polyester Materials via Statistical Learning

Abstract We employ statistical learning to present a principled framework for the establishment of quantitative structure-property relationships (QSPR). We focus on property predictions of industrial polymers formed by multiple reagents and at varying molecular weights. We develop a theoretical description of QSPR as well as a rigorous mathematical...

Sat Apr 13, 2024 15:01
An Alternative Explanation of the Microscopic Dynamics of Cyclic Polymers

Dynamic properties of cyclic polymers including non-Gaussianity, heterogeneity, and subdiffusive diffusion are at odds with the predictions from theories of motions restricted by fixed obstacles, but are hallmarks of cooperative dynamics found in entangled linear polymers, and in many other nonpolymeric materials. The Coupling Model for cooperative...

Wed Apr 3, 2024 14:17
Effect of Highly Crosslinked Domains on the Dimensions of Network Polymers

The dimensions of network polymers having highly crosslinked domains are investigated systematically. The dimensions are larger for the networks having domains rather than the corresponding randomly connected homogeneous networks. The calibrated dimensions of network polymers start to follow the master curve relationship as the network maturity index...

Fri Mar 22, 2024 12:39
Dissipative Particle Dynamics Study on the Phase Region of Spatial Gradient Materials Produced by Photoinduced Isomerization

This study uses dissipative particle dynamics simulation method to establish a model to simulate the phase separation process occurring in the photoinduced isomerization system under different influencing factors, to study the effects of different influencing factors on the gradient structure formed by the model, and to explore the mechanism of the...

Thu Mar 14, 2024 19:40

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