Wiley Online Library : Macromolecular Theory and Simulations
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Do Entangled Polymer Chains Reptate?

Abstract Neutron spin echo spectroscopy of entangled polymer melts [M. Zamponi, et al. J. Phys. Chem. B 2008, 112, 16220], and of tracer diffusion of short polymer chains in highly entangled polymer melt [M. Zamponi et al. Phys. Rev. Lett. 2021, 126, 187801.] and [M. Kruteva et al. Macromolecules 2021, 54, 11384] found the center-of-mass mean-square...

Fri May 3, 2024 12:28
Numerical Modeling and Simulation of the Nonisothermal Double Quench Phase Separation Process for the Production of Polymeric Membranes Using Polystyrene‐Cyclohexanol Polymer Solution

Double quench phase separation is prevalent in industrial polymeric membrane formation processes. The interplay of heat and mass transfer during various phase separation stages is crucial in nonisothermal double-quench processes. The phase separated pattern with initial temperature of T*  = 1.05, initial quench temperature of T*  = 1.0, and second...

Tue Apr 30, 2024 13:33
Swelling Behaviors of Natural Rubber/Solvent Systems Based on the Extended Modified Double Lattice Model

Abstract Swelling experiments were conducted on non-filler natural rubber (NR) using four solvents (toluene, cyclohexane, tetrahydrofuran (THF), and methylethylketone (MEK)) over temperatures from 10 to 70 °C. Toluene, cyclohexane, and THF, classified as effective solvents, showed swelling ratios between 3 and 7, influenced by the crosslink density...

Fri Apr 19, 2024 11:45
Numerical Analysis of the Blade Coating Process Using Non‐Newtonian Nanofluid with Magnetohydrodynamic (MHD) and Slip Effects

This study investigates non-isothermal blade coating of non-Newtonian nanofluid with magnetic, slip coefficient, thermophoresis, and Brownian effects. The effects of these parameters on the coating thickness, blade load, velocity, temperature, concentration, and pressure profiles are analyzed, revealing trends such as increased velocity near the substrate...

Thu Apr 18, 2024 11:54
Quantitative Structure‐Property Relations for Polyester Materials via Statistical Learning

Abstract We employ statistical learning to present a principled framework for the establishment of quantitative structure-property relationships (QSPR). We focus on property predictions of industrial polymers formed by multiple reagents and at varying molecular weights. We develop a theoretical description of QSPR as well as a rigorous mathematical...

Sat Apr 13, 2024 15:01
An Alternative Explanation of the Microscopic Dynamics of Cyclic Polymers

Dynamic properties of cyclic polymers including non-Gaussianity, heterogeneity, and subdiffusive diffusion are at odds with the predictions from theories of motions restricted by fixed obstacles, but are hallmarks of cooperative dynamics found in entangled linear polymers, and in many other nonpolymeric materials. The Coupling Model for cooperative...

Wed Apr 3, 2024 14:17

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