Wiley Online Library : ChemSusChem
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Triazine‐Carbazole‐Based Covalent Organic Frameworks as Efficient Heterogeneous Photocatalysts for the Oxidation of N‐aryltetrahydroisoquinolines

Covalent organic frameworks (COFs) have attracted growing interests as new material platform for a range of applications. In this study, a triazine-carbazole-based covalent organic framework (COF-TCZ) was designed as highly porous material with conjugated donor-acceptor networks, and  feasibley synthesized by the Schiff condensation of 4,4',4''-(1,3,5-triazine-2,4,6-triyl)trianiline...

Tue Apr 23, 2024 12:27
Visible‐Light‐Induced Sulfonylative‐Cyclization Cascade of 1,6‐Enynol Derivatives with Sulfinic Acids: A Sustainable Approach for the Synthesis of 2,3‐Disubstituted Benzoheteroles

Benzoheteroles are promising structural scaffolds in the realm of medicinal chemistry, but sustainable synthesis of 2,3-difunctionalized benzoheterole derivatives is still in high demand. Indeed, we have conceptually rationalized the intrinsic reactivity of propargylic-enyne systems for the flexible construction of 2,3-disubstituted benzoheteroles through...

Tue Apr 23, 2024 12:27
Optimized Transition Metal Phosphides for Direct Seawater Electrolysis: Current Trends

With the growing focus on transition metal phosphides (TMPs) in seawater splitting, this review provides a comprehensive analysis of recent progress in the surface engineering of TMPs for efficient seawater electrolysis, aiming to illustrate an insight into the synthesis-structure-property correlations and guide to the designing of highly efficient...

Tue Apr 23, 2024 12:27
Fully Bio‐Based 2,5‐Furandicarboxylic Acid Polyester toward Plastics with Mechanically Robust, Excellent Gas Barrier and Fast Degradation

Fully bio-based PBOF copolyesters formed from oxalic acid, 2,5-furandicarboxylic acid and butanediol are capable of realizing a circular carbon economy at the source. The theoretical evidence that the oxalic acid segment has the lowest hydrolysis energy barrier corresponds to the fastest hydrolysis rate, indicating that the oxalic acid segment confers...

Tue Apr 23, 2024 12:27
Reversal Effect of Phosphorus on Catalytic Performances of Supported Nickel Catalysts in Reductive Amination of 1,6‐Hexanediol

1,6-Hexamethylenediamine was produced by a green route of 1,6-hexanediol reductive amination on a phosphorus modified Ni/Al2O3 catalyst. After phosphorous modification, the amount of terrace sites of Ni increased significantly but the number of acid sites decreased, which favored for the production of HMDA, thus the selectivity to HMDA was improved...

Tue Apr 23, 2024 12:27
Challenges and Recent Progress on Solid‐State Batteries and Electrolytes, using Qualitative Systematic Analysis. A Short Review

Basics and introduction about solid-state batteries, new materials and tendencies that may step up to make solid state batteries commercially available. An overview of different materials and techniques currently used, and to guide further development. Promising results, market and environmental importance and perspectives for the next decades. ...

Tue Apr 23, 2024 12:27

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